methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Base Information

Chemical Name:methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate
CAS No.:5737-79-1
Molecular Formula:C₁₄H₁₃NO₂
Molecular Weight:227.263
Hs Code.:

Synonyms:methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Suppliers and Price of methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Methyl2'-amino-[1,1'-biphenyl]-4-carboxylate 97%
1g
$ 731.00

CHESS?
AN024401:2'-Amino-biphenyl-4-carboxylicacidmethylester 97
5 g
$ 1068.00

Total 3 raw suppliers

Chemical Property of methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Chemical Property:

Purity/Quality:: Methyl2'-amino-[1,1'-biphenyl]-4-carboxylate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

There total 14 articles about methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 5737-78-0
methyl 2'-nitro-[1,1'-biphenyl]-4-carboxylate

: 5737-79-1
methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Guidance literature:: With iron; acetic acid; In water; acetone; for 4h; Reflux;
DOI:10.1016/j.tetlet.2020.152750

Reference yield: 71.0%

: 615-36-1
2-bromoaniline

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 5737-79-1
methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Guidance literature:: 2-bromoaniline; 4-methoxycarbonylphenylboronic acid; With potassium carbonate; In 1,2-dimethoxyethane; water; at 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

With dichlorobis(tri-O-tolylphosphine)palladium; In 1,2-dimethoxyethane; water; at 80 ℃; for 12h; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.joc.8b02405

Reference yield: 65.0%

: 615-43-0
2-iodophenylamine

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 5737-79-1
methyl 2′-amino-[1,1′-biphenyl]-4-carboxylate

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; In 1,2-dimethoxyethane; water; at 80 ℃; for 18h; Inert atmosphere; Sealed tube;
DOI:10.1039/c7gc02261a