diphenylmethylphosphine-borane complex

Base Information

• Chemical Name: diphenylmethylphosphine-borane complex
• CAS No.: 54067-17-3
• Molecular Formula: C₁₃H₁₆BP
• Molecular Weight: 214.055
• Mol file: 54067-17-3.mol

Synonyms:diphenylmethylphosphine-borane complex

Chemical Property of diphenylmethylphosphine-borane complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylmethylphosphine-borane complex

There total 17 articles about diphenylmethylphosphine-borane complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenylphosphineborane (41593-58-2) → diphenylmethylphosphine-borane complex (54067-17-3)

Guidance literature:

With MeI; KOH; In methanol; room temp.;

DOI:10.1021/ja00304a061

Reference yield: 99.0%

borane tetrahydrofuran + diphenyl(methyl)phosphine (1486-28-8) → diphenylmethylphosphine-borane complex (54067-17-3)

Guidance literature:

In tetrahydrofuran; under N2, Schlenk techniques; soln. of P compd. (1.35 mmol) added to soln. of B compd. (1.30 mmol) at -78°C with stirring, warmed to roomtemp. overnight; evapd.;

DOI:10.1002/ejic.200501126

Reference yield: 96.0%

sodium tetrahydroborate (16940-66-2) + diphenyl(methyl)phosphine oxide (2129-89-7) → diphenylmethylphosphine-borane complex (54067-17-3)

Guidance literature:

With lithium aluminium tetrahydride; cerium(III) chloride; In not given; 0-25°C; according to Imamoto, T. et al., J. Am. Chem. Soc., 1985, 107, 5301; IR and (1)H-NMR spectroscopy;

DOI:10.1021/ja00169a036

upstream raw materials:

methyl iodide

iodobenzene

tetramethylammonium octahydrotriborate

[CoCl₂(PMePh₂)₂]

Downstream raw materials:

(3-methyl-3-butenyl)diphenylphosphine-borane complex

(4-methyl-3-pentenyl)diphenylphosphine-borane complex

2-(diphenylphosphanyl)-1-(pyridin-2-yl)ethanone borane adduct

(methyldiphenylphosphine)3CuCl