(methyldiphenylphosphine)3CuCl

Base Information

• Chemical Name: (methyldiphenylphosphine)3CuCl
• CAS No.: 36386-10-4
• Molecular Formula: C₃₉H₃₉ClCuP₃
• Molecular Weight: 699.659
• Mol file: 36386-10-4.mol

Synonyms:

Chemical Property of (methyldiphenylphosphine)3CuCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (methyldiphenylphosphine)3CuCl

There total 2 articles about (methyldiphenylphosphine)3CuCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

copper(l) chloride + diphenylmethylphosphine-borane complex (54067-17-3) → (methyldiphenylphosphine)3CuCl (36386-10-4)

Guidance literature:

In ethanol; under Ar; 4 equiv. of phosphine borane reacted with CuCl in EtOH; crystd. by cooling; elem. anal.;

DOI:10.1016/S0022-328X(01)00666-0

Reference yield:

diphenyl(methyl)phosphine (1486-28-8) + copper(l) chloride → (methyldiphenylphosphine)3CuCl (36386-10-4)

Guidance literature:

In dichloromethane; stoich. amts. MePh2P and CuCl mixed in small volume methylene chloride; pentane, hexane or cyclohexane added until ppt. began to form, soln. cooled in ice bath and allowed to stand for a few minutes and filtered;

Reference yield:

(methyldiphenylphosphine)3CuCl (36386-10-4) + sodium (acetoxy)trihydroborate → [(acetoxy)trihydroborato]tris(methyldiphenylphosphine)copper(I)

Guidance literature:

With 15-crown-5; In dichloromethane; to a stirred soln. of 15-crown-5 in dry methylene chlorid was added sodium(acetoxy)trihydroborate; when all of the salt dissolved, chlorotris(methyldiphenylphosphin)copper(I) was added; the mixt. was refluxed with stirring under inert atm. for 24 h; filtered and the filtrate collected; the solvent was removed by flash evapn. and to the remaining oil was added hexane; the hexane caused the product to crystallize as a solid; elem. anal.;

DOI:10.1016/S0277-5387(00)87168-5

upstream raw materials:

diphenyl(methyl)phosphine

diphenylmethylphosphine-borane complex

Downstream raw materials:

((H₃C)(C₆H₅)2P)3Cu(NC)2BH₂

(ethoxycarbonyl)(trihydroborato)tris(methyldiphenylphosphine)copper(I)