rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Base Information

Chemical Name:rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)
CAS No.:121288-64-0
Molecular Formula:C₂₄H₄₁BrIO₆P
Molecular Weight:663.368
Hs Code.:

Synonyms:rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Suppliers and Price of rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

There total 10 articles about rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 4167-02-6
2-bromoethylphosphoric acid dichloride

: 121269-41-8
rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol

: 121288-64-0
rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Guidance literature:: With pyridine; In diethyl ether; 1) 10 min, 0 deg C, 2) 4.5 h, reflux;
DOI:10.1021/jm00129a020

Reference yield:

: 99-61-6
3-nitro-benzaldehyde

: 121288-64-0
rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Guidance literature:: Multi-step reaction with 9 steps

1: 60 percent / NaNH₂ / tetrahydrofuran / 4.5 h

2: 97.5 percent / H₂ / 5percent Pd/C / ethyl acetate / 4 h / 2327.2 Torr / Ambient temperature

3: 1) glacial acetic acid, conc. HCl, NaNO₂, 2) KI, I₂ / 1) H₂O, 40 min, 0 deg C, 2) overnight, r.t.

4: 88 percent / KOH / aq. ethanol / Heating

5: 98 percent / BH₃-THF / tetrahydrofuran / 20 h / Ambient temperature

6: 71 percent / pyridine / Ambient temperature

7: 1) K / 1) benzene, 1 h, reflux, 2) overnight, reflux

8: 66 percent / 1 N HClO₄ / dioxane / 10 h / 80 - 100 °C

9: 42 percent / pyridine / diethyl ether / 1) 10 min, 0 deg C, 2) 4.5 h, reflux

With pyridine; hydrogenchloride; potassium hydroxide; perchloric acid; borane-THF; hydrogen; iodine; sodium amide; acetic acid; potassium iodide; sodium nitrite; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; ethyl acetate;
DOI:10.1021/jm00129a020

Reference yield:

: 102831-65-2
ethyl 12-(3-nitrophenyl)-11-dodecenoate

: 121288-64-0
rac-1-O-<12-(m-iodophenyl)dodecyl>-2-O-methylglycerol 3-(2'-bromoethyl phosphate)

Guidance literature:: Multi-step reaction with 8 steps

1: 97.5 percent / H₂ / 5percent Pd/C / ethyl acetate / 4 h / 2327.2 Torr / Ambient temperature

2: 1) glacial acetic acid, conc. HCl, NaNO₂, 2) KI, I₂ / 1) H₂O, 40 min, 0 deg C, 2) overnight, r.t.

3: 88 percent / KOH / aq. ethanol / Heating

4: 98 percent / BH₃-THF / tetrahydrofuran / 20 h / Ambient temperature

5: 71 percent / pyridine / Ambient temperature

6: 1) K / 1) benzene, 1 h, reflux, 2) overnight, reflux

7: 66 percent / 1 N HClO₄ / dioxane / 10 h / 80 - 100 °C

8: 42 percent / pyridine / diethyl ether / 1) 10 min, 0 deg C, 2) 4.5 h, reflux

With pyridine; hydrogenchloride; potassium hydroxide; perchloric acid; borane-THF; hydrogen; iodine; acetic acid; potassium iodide; sodium nitrite; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; ethyl acetate;
DOI:10.1021/jm00129a020