(R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

Base Information

Chemical Name:(R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol
CAS No.:115129-98-1
Molecular Formula:C₂₀H₃₂O₄Si
Molecular Weight:364.557
Hs Code.:

Synonyms:(R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

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Chemical Property of (R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

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Technology Process of (R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

There total 3 articles about (R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1224587-98-7
(3aR,6R,6aR)-6-(tert-butyldimethylsilyloxy)methyl-2,2-dimethyl-4-phenyltetrahydrofuro[3,4-d][1,3]dioxol-4-ol

: 115129-98-1
(R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

Guidance literature:: With dichloro-acetic acid; sodium cyanoborohydride; In various solvent(s); for 0.166667h; Ambient temperature;
DOI:10.1016/S0008-6215(00)90884-X

Reference yield:

: 75467-36-6
5-O-(tert-butyldimethylsilyl)-2,3-O-isopropylidene-D-ribonolactone

: 115129-98-1
(R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / tetrahydrofuran; diethyl ether / 6 h / -78 °C

2: 68 percent / sodium cyanoborohydride, dichloroacetic acid / various solvent(s) / 0.17 h / Ambient temperature

With dichloro-acetic acid; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether;
DOI:10.1016/S0008-6215(00)90884-X

Reference yield:

: 591-51-5
phenyllithium

: 115129-98-1
(R)-1,4-anhydro-5-O-<(1,1-dimethylethyl)dimethylsilyl>-2,3-O-(1-methylethylidene)-1-C-phenyl-D-ribitol

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / tetrahydrofuran; diethyl ether / 6 h / -78 °C

2: 68 percent / sodium cyanoborohydride, dichloroacetic acid / various solvent(s) / 0.17 h / Ambient temperature

With dichloro-acetic acid; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether;
DOI:10.1016/S0008-6215(00)90884-X