dimethoxomanganese(IV) tetraphenylporphyrin

Base Information

• Chemical Name: dimethoxomanganese(IV) tetraphenylporphyrin
• CAS No.: 83095-80-1
• Molecular Formula: C₄₆H₃₄MnN₄O₂
• Molecular Weight: 729.74
• Mol file: 83095-80-1.mol

Synonyms:dimethoxomanganese(IV) tetraphenylporphyrin

Chemical Property of dimethoxomanganese(IV) tetraphenylporphyrin

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethoxomanganese(IV) tetraphenylporphyrin

There total 6 articles about dimethoxomanganese(IV) tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

manganese(III) meso-tetraphenylporphyrin acetate (58356-65-3) + iodosylbenzene (536-80-1) + sodium methylate (124-41-4) → dimethoxomanganese(IV) tetraphenylporphyrin (83095-80-1)

Guidance literature:

In methanol; complex was dissolved in MeOH and soln. was filtered, NaOCH3 was added and then iodosylbenzene was added, mixt. was stirred for 1 h; ppt. was filtered off, washed with MeOH, dried in vac.; elem.anal.;

Reference yield: 74.0%

sodium hypochlorite (7681-52-9) + manganese(III) meso-tetraphenylporphyrin acetate (58356-65-3) + sodium methylate (124-41-4) → dimethoxomanganese(IV) tetraphenylporphyrin (83095-80-1)

Guidance literature:

In methanol; complex was dissolved in MeOH and soln. was filtered, NaOCH3 was added and then NaOCl was added, mixt. was standed for 1 h; ppt. was filtered off, washed with MeOH and Et2O, dried in vac.; elem.anal.;

Reference yield: 73.0%

sodium tetrahydroborate (16940-66-2) + manganese(III) meso-tetraphenylporphyrin acetate (58356-65-3) + iodosylbenzene (536-80-1) → dimethoxomanganese(IV) tetraphenylporphyrin (83095-80-1)

Guidance literature:

In methanol; complex was dissolved in MeOH and soln. was filtered, NaBH4 was added and then iodosylbenzene was added; ppt. was filtered off, washed with MeOH and hexane, dried in vac.; elem.anal.;

upstream raw materials:

sodium methylate

sodium tetrahydroborate

manganese(III) meso-tetraphenylporphyrin acetate

iodosylbenzene

Downstream raw materials:

manganese(II) 5,10,15,20-tetraphenylporphyrinate

bis(isocyanato)(5,10,15,20-tetraphenylporphinato)manganese(IV)*0.438CH₂Cl₂

isocyanato(5,10,15,20-tetraphenylporphinato)manganese(III)