(2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Base Information

Chemical Name:(2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal
CAS No.:1595172-39-6
Molecular Formula:C₁₈H₂₆N₄O₂
Molecular Weight:330.43
Hs Code.:

Synonyms:(2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

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Chemical Property of (2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

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Technology Process of (2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

There total 5 articles about (2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 2564-83-2,45842-10-2,126517-51-9,25657-03-8,26933-82-4,54637-06-8,64104-42-3
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 4648-54-8
trimethylsilylazide

: 104-55-2
3-phenyl-propenal

: 1595172-39-6
(2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

: (2S,3S)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Guidance literature:: With iron(III) chloride hexahydrate; (R)-(-)-α,α-bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanoltrimethylsilyl ether; benzoic acid; In acetonitrile; at -15 ℃; for 20h; Solvent; Reagent/catalyst; Temperature; stereoselective reaction; Green chemistry;
DOI:10.1002/ejoc.201301915

Reference yield: 56.0%

: 2564-83-2,45842-10-2,126517-51-9,25657-03-8,26933-82-4,54637-06-8,64104-42-3
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 4648-54-8
trimethylsilylazide

: 104-55-2
3-phenyl-propenal

: 1595172-39-6
(2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

: (2S,3S)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

: 3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Guidance literature:: With iron(III) chloride hexahydrate; (R)-(-)-α,α-bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanoltrimethylsilyl ether; trifluoroacetic acid; In acetonitrile; at -15 ℃; for 20h; stereoselective reaction; Green chemistry;
DOI:10.1002/ejoc.201301915

Reference yield: 3.0%

: 2564-83-2,45842-10-2,126517-51-9,25657-03-8,26933-82-4,54637-06-8,64104-42-3
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: 4648-54-8
trimethylsilylazide

: 104-55-2
3-phenyl-propenal

: 1595172-39-6
(2R,3R)-3-azido-3-phenyl-2-((2,2,6,6-tetramethylpiperidin-1-yl)oxy)propanal

Guidance literature:: With (R)-(-)-α,α-bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanoltrimethylsilyl ether; iron(III) chloride tetrahydrate; tetrabutyl ammonium fluoride; In acetonitrile; at -15 ℃; for 20h; stereoselective reaction; Green chemistry;
DOI:10.1002/ejoc.201301915