6-methyl-2-(phenylazo)pyridine

Base Information

• Chemical Name: 6-methyl-2-(phenylazo)pyridine
• CAS No.: 71291-81-1
• Molecular Formula: C₁₂H₁₁N₃
• Molecular Weight: 197.239
• Mol file: 71291-81-1.mol

Synonyms:6-methyl-2-(phenylazo)pyridine

Chemical Property of 6-methyl-2-(phenylazo)pyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 6-methyl-2-(phenylazo)pyridine

There total 1 articles about 6-methyl-2-(phenylazo)pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2-Amino-6-methylpyridine (1824-81-3) + Nitrosobenzene (586-96-9) → 6-methyl-2-(phenylazo)pyridine (71291-81-1)

Guidance literature:

With sodium hydroxide; In benzene; at 70 ℃; for 8h;

DOI:10.1039/d0dt00466a

Reference yield: 82.0%

6-methyl-2-(phenylazo)pyridine (71291-81-1) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Mo(6-methyl-2-(phenylazo)pyridine)3

Guidance literature:

In octane; Mo(CO)6 (0.90 mmol) and a ligand (2.8 mmol) were refluxed in octane for 17-24 h; the solvent was removed under vac.; the residue in CH2Cl2 was chromd. onFlorisi with acetone-petroleum ether mixt. for development; the main da rk green band was eluted with a 1/1 mixt. or more; the solvent was removed under vac.; elem. anal.;

DOI:10.1016/S0020-1693(02)00851-4

Reference yield: 60.0%

6-methyl-2-(phenylazo)pyridine (71291-81-1) → C12H10BrN3

Guidance literature:

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 12h; Reflux;

DOI:10.1039/d0dt00466a

upstream raw materials:

2-Amino-6-methylpyridine

Nitrosobenzene

Downstream raw materials:

N-(6-methyl-[2]pyridyl)-N'-phenyl-hydrazine