(E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

Base Information

Chemical Name:(E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane
CAS No.:1429227-36-0
Molecular Formula:C₃₈H₄₆O₆Si
Molecular Weight:626.865
Hs Code.:

Synonyms:(E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

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Chemical Property of (E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

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Technology Process of (E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

There total 6 articles about (E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1429227-34-8
(E)-3-benzyloxy-2-[3-(3-benzyloxy-4-methoxyphenyl)allyl]-5-methoxymethoxyphenol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1429227-36-0
(E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
DOI:10.1016/j.tetasy.2013.02.012

Reference yield:

: 1429227-33-7
(E)-1-(2-benzyloxy-6-hydroxy-4-methoxymethoxyphenyl)-3-(4-benzyloxy-3-methoxyphenyl)propenone

: 1429227-36-0
(E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: cerium(III) chloride heptahydrate; sodium tetrahydroborate / tetrahydrofuran; ethanol / 65 h / 2 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride heptahydrate; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide;
DOI:10.1016/j.tetasy.2013.02.012

Reference yield:

: 65490-09-7
2'-hydroxy-4',6'-bis(methoxymethoxy)acetophenone

: 1429227-36-0
(E)-{3-benzyloxy-2-[3-(4-benzyloxy-3-methoxyphenyl)allyl]-5-methoxymethoxyphenoxy}tert-butyldimethylsilane

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 16 h / 75 °C / Inert atmosphere

2.1: water / acetone / 5 h / Reflux

3.1: sodium hydride / n-heptane; N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 °C / Inert atmosphere

3.2: 2.17 h / 0 - 20 °C / Inert atmosphere

4.1: cerium(III) chloride heptahydrate; sodium tetrahydroborate / tetrahydrofuran; ethanol / 65 h / 2 °C / Inert atmosphere

4.2: Inert atmosphere

5.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride heptahydrate; water; sodium hydride; potassium carbonate; In tetrahydrofuran; ethanol; n-heptane; N,N-dimethyl-formamide; acetone; mineral oil; 3.1: |Aldol Condensation / 3.2: |Aldol Condensation;
DOI:10.1016/j.tetasy.2013.02.012