methyl (E)-2-(trimethylstannyl)cinnamate

Base Information

Chemical Name:methyl (E)-2-(trimethylstannyl)cinnamate
CAS No.:132363-49-6
Molecular Formula:C₁₃H₁₈O₂Sn
Molecular Weight:324.995
Hs Code.:

Synonyms:methyl (E)-2-(trimethylstannyl)cinnamate

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Chemical Property of methyl (E)-2-(trimethylstannyl)cinnamate

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Technology Process of methyl (E)-2-(trimethylstannyl)cinnamate

There total 1 articles about methyl (E)-2-(trimethylstannyl)cinnamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 1631-73-8
trimethylstannane

: 4891-38-7
phenylpropynoic acid methyl ester

: 132363-49-6
methyl (E)-2-(trimethylstannyl)cinnamate

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; flushing with Ar a mixt. of propiolate, dry THF and catalyst in a flask, sealing with a septum, dropwise addn. of the stannane in dry THF over a period of 5 min, stirring for 0.5 h; monitored by IR, removal of solvent (reduced pressure, maintaining Ar atmosphere), addn. of pentane, cooling to -10°C for 0.5 h, filtering off catalyst under Ar, removal of pentane, Kugelrohr distn. (97°C, 0.1 Torr); elem. anal.;
DOI:10.1021/om00015a031

Reference yield:

: 132363-49-6
methyl (E)-2-(trimethylstannyl)cinnamate

: 1066-45-1
trimethyltin(IV)chloride

Guidance literature:: With hydrogenchloride; In methanol; water; protodestannylation in MeOH/H2O at 25°C; monitored spectrophotometrically; Kinetics;
DOI:10.1021/om00015a031