Methyl phenylpropiolate

Base Information

Chemical Name:Methyl phenylpropiolate
CAS No.:4891-38-7
Molecular Formula:C10H8O2
Molecular Weight:160.172
Hs Code.:29163900
European Community (EC) Number:628-345-8
DSSTox Substance ID:DTXSID10197637
Nikkaji Number:J45.120G
Wikidata:Q63409032
Mol file:4891-38-7.mol

Synonyms:Methyl phenylpropiolate;4891-38-7;Methyl 3-phenylpropiolate;methyl 3-phenylprop-2-ynoate;2-Propynoic acid, 3-phenyl-, methyl ester;Phenylpropynoic acid methyl ester;METHYLPHENYLPROPIOLATE;Methyl phenylpropynoate;Phenylpropiolic Acid Methyl Ester;Propiolic acid, 3-phenyl-, methyl ester;Methyl Phenylpropargylate;Methyl 3-phenyl-2-propynoate;MFCD00041685;Methy phenylpropiolate;MethylphenYLpropaLATE;Propiolic acid, phenyl-, methyl ester;Methyl 3-phenylpropynoate;Methyl phenylethynecarboxylate;methyl-3-phenyl-2-propynoate;Methyl phenylpropiolate, 97%;SCHEMBL124863;Methyl phenylacetylenecarboxylate;2-Phenyl-1-carbomethoxyacetylene;DTXSID10197637;Phenylpropargylic Acid Methyl Ester;AKOS009159034;3-phenyl-prop-2-ynoic acid methyl ester;AS-58405;CS-0063867;FT-0628336;M2080;D70333;EN300-743466;Q63409032

Suppliers and Price of Methyl phenylpropiolate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
Methyl Phenylpropiolate >98.0%(GC)
5g
$ 92.00

TCI Chemical
Methyl Phenylpropiolate >98.0%(GC)
25g
$ 319.00

SynQuest Laboratories
Methy phenylpropiolate
100 g
$ 680.00

SynQuest Laboratories
Methy phenylpropiolate
25 g
$ 200.00

SynQuest Laboratories
Methy phenylpropiolate
5 g
$ 56.00

Sigma-Aldrich
Methyl phenylpropiolate 97%
5g
$ 76.70

Crysdot
Methyl3-phenylpropiolate 95+%
100g
$ 556.00

Apolloscientific
Methyphenylpropiolate 98%
25g
$ 173.00

Apolloscientific
Methyphenylpropiolate 98%
5g
$ 47.00

Apolloscientific
Methyphenylpropiolate 98%
100g
$ 591.00

Total 30 raw suppliers

Chemical Property of Methyl phenylpropiolate

Chemical Property:

Appearance/Colour:clear colorless to pale yellow liquid
Vapor Pressure:0.025mmHg at 25°C
Melting Point:26°C
Refractive Index:n20/D 1.5590(lit.)
Boiling Point:247.9 °C at 760 mmHg
Flash Point:117.4 °C
PSA：26.30000
Density:1.12 g/cm³
LogP:1.21110
Storage Temp.:Inert atmosphere,Room Temperature
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:160.052429494
Heavy Atom Count:12
Complexity:213

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl Phenylpropiolate >98.0%(GC) ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/38
Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC(=O)C#CC1=CC=CC=C1
Uses Methyl phenylpropiolate may be used in the synthesis of:bicyclohexadienescis-methyl cinnamate(E)-alkyl 3-(dialkoxyphosphoryl)-3-phenylacrylate derivatives

Technology Process of Methyl phenylpropiolate

There total 67 articles about Methyl phenylpropiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 637-44-5
phenylpropyolic acid

: 4891-38-7
phenylpropynoic acid methyl ester

Guidance literature:: In diethyl ether;
DOI:10.1039/b822944a

Reference yield: 98.0%

: 637-44-5
phenylpropyolic acid

: 74-88-4
methyl iodide

: 4891-38-7
phenylpropynoic acid methyl ester

Guidance literature:: With potassium carbonate; In acetonitrile; at 20 ℃; for 3h;

Reference yield: 95.0%

: 591-50-4
iodobenzene

: 922-67-8
propynoic acid methyl ester

: 4891-38-7
phenylpropynoic acid methyl ester

Guidance literature:: propynoic acid methyl ester; With zinc dibromide; lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

iodobenzene; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 23 ℃; Further stages.;
DOI:10.1021/ol010145q