monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide

Base Information

• Chemical Name: monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide
• CAS No.: 404892-90-6
• Molecular Formula: C₂₃H₁₈Cl₂OTi
• Molecular Weight: 429.181
• Mol file: 404892-90-6.mol

Synonyms:monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide

Chemical Property of monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide

Chemical Property:

Purity/Quality:

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Technology Process of monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide

There total 1 articles about monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

cyclopentadienyl titanium(IV) trichloride (1270-98-0) + (1,1';3',1''-terphenyl)-2'-ol (2432-11-3) → monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide (404892-90-6)

Guidance literature:

With triethylamine; In diethyl ether; (Ar); addn. of NEt3 to a soln. of titanium compd. and ligand in Et2O at 25°C, stirring for 12 h; filtration, washing solids with Et2O, concn., recrystn. by layering toluene soln. with hexanes; elem. anal.;

DOI:10.1021/om010755u

Reference yield:

monocyclopentadienyltitanium dichloride 2,6-diphenylphenoxide (404892-90-6) + hept-6-en-1-ynylbenzene (19016-85-4) → C5H5Ti[OC6(C6H5)2H3]C(C6H5)C(CH2)3CHCH2 (404892-96-2)

Guidance literature:

With n-butyllithium; In not given; reacting enyne with Ti complex and BuLi from -78 to 25°C for 3h; not isolated, detected by NMR;

DOI:10.1021/om010755u

upstream raw materials:

cyclopentadienyl titanium(IV) trichloride

(1,1';3',1''-terphenyl)-2'-ol

Downstream raw materials:

C₅H₅Ti[OC₆(C₆H₅)2H₃]C(C₆H₅)C(CH₂)3CHCH₂