1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

Base Information

Chemical Name:1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol
CAS No.:132255-68-6
Molecular Formula:C₁₈H₃₂O₃Si₂
Molecular Weight:352.621
Hs Code.:

Synonyms:1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

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Technology Process of 1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

There total 3 articles about 1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 4071-88-9
trimethylsilanyl-acetic acid ethyl ester

: 132255-78-8
4-(tert.-Butyldimethylsilyloxy)-3-methoxyacetophenon

: 132255-68-6
1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; 1) -78 deg C, 3 h, 2) to 0 deg C, 1 h, 3) 0 deg C, 2 h;
DOI:10.1002/ardp.19903231208

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 132255-68-6
1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / Imidazole / dimethylformamide / 3 h / Ambient temperature

2: 72 percent / Tetrabutylammoniumfluoride / tetrahydrofuran / 1) -78 deg C, 3 h, 2) to 0 deg C, 1 h, 3) 0 deg C, 2 h

With 1H-imidazole; tetrabutyl ammonium fluoride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/ardp.19903231208

Reference yield:

: 498-02-2
1-(3-methoxy-4-hydroxyphenyl)ethanone

: 132255-68-6
1-(tert.-Butyldimethylsilyloxy)-2-methoxy-4-(1-trimethylsilyloxyethenyl)-benzol

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / Imidazole / dimethylformamide / 3 h / Ambient temperature

2: 72 percent / Tetrabutylammoniumfluoride / tetrahydrofuran / 1) -78 deg C, 3 h, 2) to 0 deg C, 1 h, 3) 0 deg C, 2 h

With 1H-imidazole; tetrabutyl ammonium fluoride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/ardp.19903231208