7-Phenylsulfanyl-bicyclo[3.2.0]hept-2-en-6-one (racemic)

Base Information

Chemical Name:7-Phenylsulfanyl-bicyclo[3.2.0]hept-2-en-6-one (racemic)
CAS No.:76822-08-7
Molecular Formula:C₁₃H₁₂OS
Molecular Weight:216.304
Hs Code.:
Mol file:76822-08-7.mol

Synonyms:Bicyclo[3.2.0]hept-2-en-6-one,7-(phenylthio)-, (1a,5a,7b)-(?à)-; Bicyclo[3.2.0]hept-2-en-6-one, 7-(phenylthio)-, (1a,5a,7b)-

Suppliers and Price of 7-Phenylsulfanyl-bicyclo[3.2.0]hept-2-en-6-one (racemic)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
7-PHENYLSULFANYL-BICYCLO[3.2.0]HEPT-2-EN-6-ONE 95.00%
10G
$ 4735.50

American Custom Chemicals Corporation
7-PHENYLSULFANYL-BICYCLO[3.2.0]HEPT-2-EN-6-ONE 95.00%
5G
$ 3580.50

American Custom Chemicals Corporation
7-PHENYLSULFANYL-BICYCLO[3.2.0]HEPT-2-EN-6-ONE 95.00%
1G
$ 1726.73

Total 5 raw suppliers

Chemical Property of 7-Phenylsulfanyl-bicyclo[3.2.0]hept-2-en-6-one (racemic)

Chemical Property:

PSA：42.37000
LogP:2.92230

Purity/Quality:

99% ^*data from raw suppliers

7-PHENYLSULFANYL-BICYCLO[3.2.0]HEPT-2-EN-6-ONE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 7-Phenylsulfanyl-bicyclo[3.2.0]hept-2-en-6-one (racemic)

There total 5 articles about 7-Phenylsulfanyl-bicyclo[3.2.0]hept-2-en-6-one (racemic) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 7031-27-8
(phenylthio)acetic acid chloride

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 55834-30-5,76822-08-7,92998-65-7
endo-7-(phenylthio)bicyclo<3.2.0>hept-2-en-6-one

Guidance literature:: With triethylamine; In diethyl ether; at 25 ℃; for 29h;
DOI:10.1021/jo000227c

Reference yield:

: 72228-26-3
S-phenyl 2-diazoethanethiolate

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 55834-30-5,76822-08-7,92998-65-7
7-(phenylthio)bicyclo[3.2.0]hept-2-en-6-one

: 7-(phenylthio)bicyclo[3.2.0]hept-2-en-6-one

Guidance literature:: With dirhodium tetraacetate; In dichloromethane; at 40 ℃; for 2.5h;
DOI:10.1021/jo000227c

Reference yield:

: 934-87-2
S-phenyl thioacetate

: 55834-30-5,76822-08-7,92998-65-7
7-(phenylthio)bicyclo[3.2.0]hept-2-en-6-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium hexamethyldisilazide / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: tetrahydrofuran; hexane / 0.17 h / -78 °C

2.1: 0.885 g / triethylamine; methanesulfonyl azide / acetonitrile; H₂O / 2.5 h / 25 °C

3.1: Rh₂(OAc)4 / CH₂Cl₂ / 2.5 h / 40 °C

With dirhodium tetraacetate; triethylamine; Methanesulfonyl azide; lithium hexamethyldisilazane; In tetrahydrofuran; hexane; dichloromethane; water; acetonitrile; 1.1: Metallation / 1.2: Acylation / 2.1: Substitution / 3.1: Cycloaddition;
DOI:10.1021/jo000227c