5-Methyl-allyl-furfuryl alcohol

Base Information

• Chemical Name: 5-Methyl-allyl-furfuryl alcohol
• CAS No.: 65223-07-6
• Molecular Formula: C9H12 O2
• Molecular Weight: 152.19
• European Community (EC) Number: 817-846-9
• Nikkaji Number: J106.092I
• Mol file: 65223-07-6.mol

Synonyms:65223-07-6;SCHEMBL9788333;5-methyl-allyl-furfuryl alcohol;WYWAZUBJTKJQMD-UHFFFAOYSA-N;5-methyl-alpha-allylfurfuryl alcohol;alpha-Allyl-5-methylfuran-2-methanol;AKOS018291168;2-(1-hydroxy-3-butenyl)-5-methylfuran

Chemical Property of 5-Methyl-allyl-furfuryl alcohol

Chemical Property:

• PSA: 33.37000
• LogP: 2.19750
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 152.083729621
• Heavy Atom Count: 11
• Complexity: 134

Purity/Quality:

99.0.% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(O1)C(CC=C)O

Technology Process of 5-Methyl-allyl-furfuryl alcohol

There total 10 articles about 5-Methyl-allyl-furfuryl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.2%

→ 2-(1-hydroxy-3-butenyl)-5-methylfuran (65223-07-6)

Guidance literature:

Reference yield: 98.0%

5-Methylfurfural (620-02-0) + 3-chloroprop-1-ene (107-05-1) → 2-(1-hydroxy-3-butenyl)-5-methylfuran (65223-07-6)

Guidance literature:

With sulfuric acid; acetic acid; In tetrahydrofuran; toluene;

Reference yield: 96.1%

5-Methylfurfural (620-02-0) → 2-(1-hydroxy-3-butenyl)-5-methylfuran (65223-07-6)

Guidance literature:

With magnesium;

upstream raw materials:

5-Methylfurfural

allylmagnesium bromide

allyltributylstanane

tetrapentylammonium chloride

Downstream raw materials:

l-2-allyl-3-hydroxy-3-methyl-4-cyclopentenone

Refernces

• 1、 Ghosh, Arun K.,Chen, Zhi-Hua,Effenberger, Kerstin A.,Jurica, Melissa S.. "Enantioselective total syntheses of fr901464 and spliceostatin a and evaluation of splicing activity of key derivatives". . p. 5697 - 5709. Retrieved 2014/07/08.
• 2、 Flynn, Daniel L.,Crich, Joyce Z.,Devraj, Rajesh V.,Hockerman, Susan L.,Parlow, John J.,South, Michael S.,Woodard, Scott. "Chemical library purification strategies based on principles of complementary molecular reactivity and molecular recognition". . p. 4874 - 4881. Retrieved 2007/10/03.