methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

Base Information

Chemical Name:methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate
CAS No.:1607814-78-7
Molecular Formula:C₂₀H₁₈O₇
Molecular Weight:370.359
Hs Code.:

Synonyms:methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

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Chemical Property of methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

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Technology Process of methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

There total 6 articles about methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1607814-75-4
2-{3-[3-methoxy-2-(methoxymethoxy)phenyl]prop-2-ynoyl}phenyl methyl carbonate

: 1607814-78-7
methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

Guidance literature:: With tributylphosphine; In toluene; at 30 ℃; for 1h; Inert atmosphere;
DOI:10.1016/j.tet.2014.03.073

Reference yield:

: 533-58-4
2-Iodophenol

: 1607814-78-7
methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) iodide; triethylamine / N,N-dimethyl-formamide / 12 h / 80 °C / 38002.6 Torr / Autoclave

3: tributylphosphine / toluene / 1 h / 30 °C / Inert atmosphere

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tributylphosphine; triethylamine; In dichloromethane; N,N-dimethyl-formamide; toluene; 2: |Sonogashira Cross-Coupling;
DOI:10.1016/j.tet.2014.03.073

Reference yield:

: 1607814-72-1
2-iodophenyl methyl carbonate

: 1607814-78-7
methyl 2-[3-methoxy-2-(methoxymethoxy)phenyl]-4-oxo-4H-chromene-3-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) iodide; triethylamine / N,N-dimethyl-formamide / 12 h / 80 °C / 38002.6 Torr / Autoclave

2: tributylphosphine / toluene / 1 h / 30 °C / Inert atmosphere

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tributylphosphine; triethylamine; In N,N-dimethyl-formamide; toluene; 1: |Sonogashira Cross-Coupling;
DOI:10.1016/j.tet.2014.03.073