(R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

Base Information

Chemical Name:(R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol
CAS No.:1271332-59-2
Molecular Formula:C₃₈H₄₀O₆
Molecular Weight:592.732
Hs Code.:

Synonyms:(R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

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Technology Process of (R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

There total 1 articles about (R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 76-83-5
trityl chloride

: 583843-85-0
(R)-1-((3aR,5R,6R,6aR)-6-Allyl-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethane-1,2-diol

: 1271332-59-2
(R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/j.tetasy.2010.11.027

Reference yield:

: 1271332-59-2
(R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

: C₃₈H₄₂O₈

Guidance literature:: With osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; In acetone; tert-butyl alcohol; at 20 ℃; for 12h;
DOI:10.1016/j.tetasy.2010.11.027

Reference yield:

: 1271332-59-2
(R)-1-((3aR,5R,6R,6aR)-6-allyl-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-(trityloxy)ethanol

: 1271332-77-4
(3aR,5R,6R,6aR)-5-((R)-2-azido-1-(benzyloxy)ethyl)-6-(benzyloxy)-6-(2-(benzyloxy)ethyl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole

Guidance literature:: Multi-step reaction with 7 steps

1.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 12 h / 20 °C

2.1: sodium periodate / methanol; water / 0 - 20 °C

3.1: sodium tetrahydroborate / methanol / 2 h / 0 - 20 °C

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 °C

4.2: 0 - 20 °C

5.1: silica supported perchloric acid / methanol / 3 h / 20 °C

6.1: dmap; triethylamine / dichloromethane / 1 h / 0 °C

7.1: sodium azide / N,N-dimethyl-formamide / 3 h / 120 °C

With dmap; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; sodium azide; silica supported perchloric acid; water; sodium hydride; 4-methylmorpholine N-oxide; triethylamine; In methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; mineral oil; tert-butyl alcohol;
DOI:10.1016/j.tetasy.2010.11.027