.alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate

Base Information

Chemical Name:.alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate
CAS No.:65058-34-6
Molecular Formula:C28H38 O18 S
Molecular Weight:694.665
Hs Code.:

Synonyms:.alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate

Suppliers and Price of .alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of .alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate

Chemical Property:

Melting Point:170 °C
Boiling Point:681.9±55.0 °C(Predicted)
PSA：254.16000
Density:1.38±0.1 g/cm3(Predicted)
LogP:-0.11420

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of .alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate

There total 10 articles about .alpha.-D-Glucopyranoside, 2,3,4,6-tetra-O-acetyl-.beta.-D-glucopyranosyl 1-thio-, tetraacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 17317-98-5,18977-84-9,68667-06-1,68778-86-9,68778-87-0,68778-88-1,108392-13-8,62853-32-1,80441-61-8
1-thio-α,α-trehalose

: 108-24-7
acetic anhydride

: 5505-45-3,18968-43-9,18968-44-0,62853-33-2,65058-34-6,68736-77-6,68736-78-7,68736-79-8,68736-80-1,103189-12-4,120331-62-6
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-glucopyranoside

Guidance literature:: With pyridine; at 20 ℃;
DOI:10.1016/j.tetlet.2012.05.159

Reference yield: 86.0%

: 19879-84-6
tetraacetyl thioglucose

: 604-69-3
β-D-glucose pentaacetate

: 65058-34-6
(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

: 5505-45-3
2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 18h; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.carres.2009.03.017

Reference yield: 50.0%

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 65058-34-6
(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

: 19879-84-6
tetraacetyl thioglucose

Guidance literature:: With carbon disulfide; sodiumsulfide nonahydrate; In N,N-dimethyl-formamide; at 20 ℃; for 0.0833333h; stereoselective reaction;
DOI:10.1021/jo302115k