Technology Process of C65H118O9Si3
There total 6 articles about C65H118O9Si3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
dimethylsulfide borane complex; (R)-proline derived oxazaborolidine;
In
tetrahydrofuran;
at 0 ℃;
for 0.333333h;
DOI:10.1016/S0040-4039(98)01192-7
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 2,6-lutidine / CH2Cl2 / 3 h / -78 °C
2: 95 percent / 1.) NaH; n-BuLi; 2.) HMPA / tetrahydrofuran / 1.) 0 deg C, 90 min; 0 deg C, 30 min;, 2.) -78 deg C, 1 h
3: 80 percent / 1.) Ba(OH)2 / 1.) THF, 20 deg C, 30 min; 2.) THF, H2O, 20 deg C, 2.5 h
4: 83 percent / (R)-proline derived oxazaborolidine, BH3*Me2S / tetrahydrofuran / 0.33 h / 0 °C
With
2,6-dimethylpyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; barium dihydroxide; n-butyllithium; dimethylsulfide borane complex; (R)-proline derived oxazaborolidine; sodium hydride;
In
tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(98)01192-7
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 2,6-lutidine / CH2Cl2 / 3 h / -78 °C
2: 95 percent / 1.) NaH; n-BuLi; 2.) HMPA / tetrahydrofuran / 1.) 0 deg C, 90 min; 0 deg C, 30 min;, 2.) -78 deg C, 1 h
3: 80 percent / 1.) Ba(OH)2 / 1.) THF, 20 deg C, 30 min; 2.) THF, H2O, 20 deg C, 2.5 h
4: 83 percent / (R)-proline derived oxazaborolidine, BH3*Me2S / tetrahydrofuran / 0.33 h / 0 °C
With
2,6-dimethylpyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; barium dihydroxide; n-butyllithium; dimethylsulfide borane complex; (R)-proline derived oxazaborolidine; sodium hydride;
In
tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(98)01192-7
