Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane

Base Information

• Chemical Name: Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane
• CAS No.: 212498-27-6
• Molecular Formula: C₃₃H₂₄F₈O₃P₂PdS
• Molecular Weight: 820.973
• Mol file: 212498-27-6.mol

Synonyms:Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane

Chemical Property of Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane

There total 1 articles about Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

Pd(II) pentafluorophenyl Cl 1,2-bis(diphenylphosphino)ethane (65856-99-7) + silver trifluoromethanesulfonate (2923-28-6) → Pd(II) pentafluorophenyl(OSO2CF3) 1,2-bis(diphenylphosphino)ethane (212498-27-6)

Guidance literature:

In not given; byproducts: AgCl; mixed, filtered; XRD, NMR;

DOI:10.1039/b008811k

Reference yield:

Pd(SC6F5)(C6F5)(C10H8N2) (212497-45-5) + Pd(2+)*O3SCF3(1-)*C6F5(1-)*(C6H5)2PCH2CH2P(C6H5)2=Pd(OSO2CF3)(C6F5)((C6H5)2PCH2CH2P(C6H5)2) (212498-27-6) → [Pd(C6F5)(bipy)(μ-SC6F5)Pd(C6F5)(dppe)]CF3SO3 (212497-68-2)

Guidance literature:

In dichloromethane; stirring equimolar amts. for 50 h; evapn., hexane addn., collection (filtration), washing (ether), drying (vac.);

Reference yield:

Pd(SC6F5)(C6F5)(C12H8N2) (212497-48-8) + Pd(2+)*O3SCF3(1-)*C6F5(1-)*(C6H5)2PCH2CH2P(C6H5)2=Pd(OSO2CF3)(C6F5)((C6H5)2PCH2CH2P(C6H5)2) (212498-27-6) → [Pd(C6F5)(phen)(μ-SC6F5)Pd(C6F5)(dppe)]CF3SO3 (212497-74-0)

Guidance literature:

In dichloromethane; stirring equimolar amts. for 50 h; evapn., hexane addn., collection (filtration), washing (ether), drying (vac.);

upstream raw materials:

Pd(II) pentafluorophenyl Cl 1,2-bis(diphenylphosphino)ethane

silver trifluoromethanesulfonate

Downstream raw materials:

[Pd(C6F5)(bipy)(μ-SC6F5)Pd(C6F5)(dppe)]CF3SO3

[Pd(C6F5)(phen)(μ-SC6F5)Pd(C6F5)(dppe)]CF3SO3