5-(Benzyloxy)-2-forMylphenylboronic acid

Base Information

Chemical Name:5-(Benzyloxy)-2-forMylphenylboronic acid
CAS No.:1226773-36-9
Molecular Formula:C₁₄H₁₃BO₄
Molecular Weight:256.066
Hs Code.:2931900090
Mol file:1226773-36-9.mol

Synonyms:(5-(benzyloxy)-2-formylphenyl)boronic acid

Suppliers and Price of 5-(Benzyloxy)-2-forMylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
5-(Benzyloxy)-2-formylphenylboronicAcid
100mg
$ 85.00

SynChem
5-(Benzyloxy)-2-formylphenylboronic acid 95%
1 g
$ 175.00

Alichem
(5-(Benzyloxy)-2-formylphenyl)boronicacid
5g
$ 497.70

AK Scientific
5-(Benzyloxy)-2-formylphenylboronicacid
5g
$ 917.00

Total 7 raw suppliers

Chemical Property of 5-(Benzyloxy)-2-forMylphenylboronic acid

Chemical Property:

Storage Temp.:2-8°C

Purity/Quality:

95+% ^*data from raw suppliers

5-(Benzyloxy)-2-formylphenylboronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5-(Benzyloxy)-2-forMylphenylboronic acid

There total 5 articles about 5-(Benzyloxy)-2-forMylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.1%

: 1226773-35-8
C₁₆H₁₅BrO₃

: 1226773-36-9
(5-(benzyloxy)-2-formylphenyl)boronic acid

Guidance literature:: C₁₆H₁₅BrO₃; With n-butyllithium; Triisopropyl borate; In tetrahydrofuran; at -80 - 20 ℃; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; water; for 2h;
DOI:10.1021/jm101225g

Reference yield: 47.0%

: 4-(benzyloxy)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

: 1226773-36-9
(5-(benzyloxy)-2-formylphenyl)boronic acid

Guidance literature:: 4-(benzyloxy)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde; With sodium periodate; In tetrahydrofuran; water; at 20 ℃; for 0.333333h;

With hydrogenchloride; In water; at 20 ℃; for 2h;
DOI:10.1039/d1cc03026d

Reference yield:

: 59142-68-6
2-bromo-4-fluorobenzaldehyde

: 1226773-36-9
(5-(benzyloxy)-2-formylphenyl)boronic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: toluene-4-sulfonic acid / toluene / 4 h / Reflux

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 4 h / 65 °C / Cooling; Inert atmosphere

3.1: n-butyllithium; Triisopropyl borate / tetrahydrofuran / -80 - 20 °C / Inert atmosphere

3.2: 2 h

With n-butyllithium; Triisopropyl borate; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; mineral oil;
DOI:10.1021/jm101225g