(2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Base Information

Chemical Name:(2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene
CAS No.:114060-33-2
Molecular Formula:C₂₂H₃₂O₅S
Molecular Weight:408.559
Hs Code.:

Synonyms:(2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

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Chemical Property of (2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

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Technology Process of (2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

There total 3 articles about (2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 68690-36-8
(2E)-6-hydroxy-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

: 114060-33-2
(2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Guidance literature:: With dmap; In dichloromethane; for 4h;
DOI:10.1021/ja00221a040

Reference yield:

: 53254-60-7
3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene

: 114060-33-2
(2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / m-CPBA / CH₂Cl₂ / 0.25 h / 0 °C

2: 86 percent / Al(O-i-Pr)3 / toluene; propan-2-ol / 20 h / 110 °C / Heating

3: 81 percent / 4-(dimethylamino)pyridine / CH₂Cl₂ / 4 h

With dmap; aluminum isopropoxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; isopropyl alcohol; toluene;
DOI:10.1021/ja00221a040

Reference yield:

: 114060-23-0
(2E)-6,7-epoxy-3,7-dimethyl-1-(p-tolylsulfonyl)-2-octene

: 114060-33-2
(2E)-6-<(tert-butoxycarbonyl)oxy>-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / Al(O-i-Pr)3 / toluene; propan-2-ol / 20 h / 110 °C / Heating

2: 81 percent / 4-(dimethylamino)pyridine / CH₂Cl₂ / 4 h

With dmap; aluminum isopropoxide; In dichloromethane; isopropyl alcohol; toluene;
DOI:10.1021/ja00221a040