(2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

Base Information

Chemical Name:(2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate
CAS No.:1234579-95-3
Molecular Formula:C₃₃H₆₃N₃O₇Si₃
Molecular Weight:698.136
Hs Code.:

Synonyms:(2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

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Chemical Property of (2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

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Technology Process of (2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

There total 1 articles about (2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 75-77-4
chloro-trimethyl-silane

: C₂₇H₄₇N₃O₇Si

: 1234579-95-3
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

Guidance literature:: With 1H-imidazole; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/chem.201000104

Reference yield: 97.0%

: 1234579-95-3
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

: 1234579-97-5
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-3-hydroxy-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2-(trimethylsilyloxy)hexanoate

Guidance literature:: With fluorosilicic acid; water; In acetonitrile; at -30 ℃; for 1.5h; Inert atmosphere;
DOI:10.1002/chem.201000104

Reference yield: 93.0%

: 1234579-95-3
(2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate

: 115491-93-5
diallyl dicarbonate

: 1234580-01-8
(2S,3R,5R)-ethyl 2-(2-(allyloxycarbonylamino)ethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis-(trimethylsilyloxy)hexanoate

Guidance literature:: (2S,3R,5R)-ethyl 2-(2-azidoethyl)-6-(4-methoxybenzyloxy)-5-(triisopropylsilyloxy)-2,3-bis(trimethylsiloxy)hexanoate; With triphenylphosphine; In tetrahydrofuran; water; at 20 ℃; for 10h;

diallyl dicarbonate; With water; sodium hydrogencarbonate; In tetrahydrofuran; at 20 ℃; for 0.166667h;
DOI:10.1002/chem.201000104