N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

Base Information

Chemical Name:N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine
CAS No.:345666-62-8
Molecular Formula:C₂₈H₅₁NO₂SSiSn
Molecular Weight:612.58
Hs Code.:

Synonyms:N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

Suppliers and Price of N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

There total 2 articles about N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 17955-46-3
trimethylsilyltributyltin

: 133886-40-5
N-tosyl-N-allylpropargylamine

: 345666-62-8
N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

Guidance literature:: In not given; react. Me3SiSnBu3 and enyne at room temp. for 16 h in the presence of Pd(OH)2/C;
DOI:10.1021/om000979x

Reference yield: 50.0%

: 17955-46-3
trimethylsilyltributyltin

: 133886-40-5
N-tosyl-N-allylpropargylamine

: 613686-47-8
CH₂CHCH₂N(SO₂C₆H₄CH₃)CH₂C(Sn(C₄H₉)3)CHSi(CH₃)3

: 345666-62-8
N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; In 1,2-dichloro-ethane; (Ar); at 40°C for 1.5-2.5 h;
DOI:10.1016/S0022-328X(03)00601-6

Reference yield: 89.0%

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 345666-62-8
N-p-toluenesulfonyl-4-(tributylstannyl)methyl-3-(E)-(trimethylsilyl)-methylidenepyrrolidine

: (2S,3S,7R)-5-(Toluene-4-sulfonyl)-7-tributylstannanylmethyl-2-trimethylsilanyl-1-oxa-5-aza-spiro[2.4]heptane

Guidance literature:: In dichloromethane; (Ar); m-CPBA added to a soln. of Sn compd. at 0°C, stirred at room temp. for 5 h; aq. soln. of Na2S2O3 added, extd. (CH2Cl2), the combined org. layer washed with satd. aq. soln. of NaHCO3, brined, dried (MgSO4), solvent-removed, chromd. (silica gel, hexane/EtOAc);
DOI:10.1016/S0022-328X(03)00601-6