(2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)Zr(NMe₂)2

Base Information

• Chemical Name: (2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)Zr(NMe₂)2
• CAS No.: 173163-38-7
• Molecular Formula: C₃₁H₅₂N₄Zr
• Molecular Weight: 572.005
• Mol file: 173163-38-7.mol

Synonyms:(2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)Zr(NMe₂)2

Chemical Property of (2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)Zr(NMe₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)Zr(NMe₂)2

There total 1 articles about (2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)Zr(NMe₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

tetrakis(dimethylamido)zirconium (IV) (19756-04-8) + 2,6-(isopropyl)2C6H3-NH-(CH2)3-NH-2,6-(isopropyl)2C6H3 → (2,6-(isopropyl)2C6H3-N-(CH2)3-N-2,6-(isopropyl)2C6H3)Zr(NMe2)2 (173163-38-7)

Guidance literature:

In toluene; N2-atmosphere; 110°C (3 h); evapn. (vac.), extg. (pentane), filtering, crystn. on concg. (-30°C, 12 h), filtering, drying (vac.); elem. anal.;

DOI:10.1021/om9703503

Reference yield: 99.0%

(2,6-(isopropyl)2C6H3-N-(CH2)3-N-2,6-(isopropyl)2C6H3)Zr(NMe2)2 (173163-38-7) + N,N-dimethylammonium chloride (506-59-2) → (2,6-(isopropyl)2C6H3-N-(CH2)3-N-2,6-(isopropyl)2C6H3)ZrCl2(dimethylamine)2 (173163-39-8)

Guidance literature:

In dichloromethane; N2-atmosphere; stirring (room temp., overnight); evapn., toluene addn., filtering, pptn. on concg. and hexane addn., filtering;

DOI:10.1021/om9703503

Reference yield: 99.0%

isopropyl isobutyrate (617-50-5) + (2,6-(isopropyl)2C6H3-N-(CH2)3-N-2,6-(isopropyl)2C6H3)Zr(NMe2)2 (173163-38-7) → [((2,6-(i-Pr)2C6H4)N(CH2)3N(2,6-(i-Pr)2C6H4))Zr(O=C(NMe2)CHMe2)(O-i-Pr)2] (1075682-66-4)

Guidance literature:

In hexane; (Ar); Schlenk technique; isopropyl isobutyrate was added to soln. of Zr complex in hexane at -30°C; stirred via pipet; warmed to room temp.; stirred for 2 h; volatiles removed (vac.); elem. anal.;

DOI:10.1021/om800602s

upstream raw materials:

tetrakis(dimethylamido)zirconium (IV)

Downstream raw materials:

(2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)ZrCl₂(pyridine)2

((((CH₃)2CH)2C₆H₃N)2(CH₂)3)Zr(Cl)2

(2,6-(isopropyl)2C₆H₃-N-(CH₂)3-N-2,6-(isopropyl)2C₆H₃)ZrCl₂(dimethylamine)2

[((2,6-(i-Pr)2C₆H₄)N(CH₂)3N(2,6-(i-Pr)2C₆H₄))Zr(O=C(NMe₂)CHMe₂)(O-i-Pr)2]