methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

Base Information

Chemical Name:methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate
CAS No.:98260-62-9
Molecular Formula:C₁₆H₁₇F₃O₉S
Molecular Weight:442.367
Hs Code.:

Synonyms:methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

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Chemical Property of methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

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Technology Process of methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

There total 6 articles about methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 16895-86-6
3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose-5,6-carbonate

: 98260-62-9
methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: acid resin (Dowex 50W-XH) / methanol / 12 h / Heating

2: pyridine / CH₂Cl₂; pyridine / 0.25 h / -30 °C

With pyridine; acid resin (Dowex 50W-XH); In pyridine; methanol; dichloromethane;
DOI:10.1016/S0040-4020(01)90034-1

Reference yield:

: 18685-18-2
3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose

: 98260-62-9
methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

Guidance literature:: Multi-step reaction with 4 steps

1: hydrochloric acid / methanol; H₂O / 20 h / Ambient temperature

2: sodium methoxide / 3 h / Heating

3: acid resin (Dowex 50W-XH) / methanol / 12 h / Heating

4: pyridine / CH₂Cl₂; pyridine / 0.25 h / -30 °C

With pyridine; hydrogenchloride; acid resin (Dowex 50W-XH); sodium methylate; In pyridine; methanol; dichloromethane; water;
DOI:10.1016/S0040-4020(01)90034-1

Reference yield:

: 582-52-5
1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

: 98260-62-9
methyl 3-O-benzyl-2-O-trifluoromethanesulphonyl-α-D-glucofuranoside-5,6-carbonate

Guidance literature:: Multi-step reaction with 5 steps

1: tetrabutylammonium iodide, sodium hydride / tetrahydrofuran / 0.75 h / Heating

2: hydrochloric acid / methanol; H₂O / 20 h / Ambient temperature

3: sodium methoxide / 3 h / Heating

4: acid resin (Dowex 50W-XH) / methanol / 12 h / Heating

5: pyridine / CH₂Cl₂; pyridine / 0.25 h / -30 °C

With pyridine; hydrogenchloride; acid resin (Dowex 50W-XH); sodium methylate; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; pyridine; methanol; dichloromethane; water;
DOI:10.1016/S0040-4020(01)90034-1