methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

Base Information

Chemical Name:methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside
CAS No.:115152-48-2
Molecular Formula:C₁₈H₂₁ClO₇S
Molecular Weight:416.88
Hs Code.:

Synonyms:methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

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Technology Process of methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

There total 2 articles about methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 115152-47-1
methyl 4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

: 75-36-5
acetyl chloride

: 115152-48-2
methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

Guidance literature:: In pyridine; dichloromethane; at 0 ℃; for 2h;
DOI:10.1016/0008-6215(88)80046-6

Reference yield:

: 104992-63-4
Methyl 4,6-O-benzylidene-1-thio-β-D-galactopyranoside

: 115152-48-2
methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 59 percent / pyridine; CH₂Cl₂ / 1 h / 0 °C

2: 89 percent / pyridine; CH₂Cl₂ / 2 h / 0 °C

In pyridine; dichloromethane;
DOI:10.1016/0008-6215(88)80046-6

Reference yield:

: 115152-48-2
methyl 2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-1-thio-β-D-galactopyranoside

: 115152-52-8,129519-30-8
ethyl 4-O-<2-O-acetyl-4,6-O-benzylidene-3-O-(chloroacetyl)-β-D-galactopyranosyl>-6-O-benzyl-2-deoxy-3-O-(p-methoxybenzyl)-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) bromine, tetraethylammonium bromide / 1.) dichloromethane; dichloromethane, r.t., 3 h

2: 74 percent / silver triflate, 2,6-di-tert-butyl-4-methylpyridine, molecular sieves 4A / toluene; CH₂Cl₂

With 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; tetraethylammonium bromide; bromine; silver trifluoromethanesulfonate; In dichloromethane; toluene;
DOI:10.1016/0008-6215(88)80046-6