tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

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Chemical Name:tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane
CAS No.:121353-13-7
Molecular Formula:C₂₉H₄₀O₃Si
Molecular Weight:464.72
Hs Code.:

Synonyms:tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

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Chemical Property of tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

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Technology Process of tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

There total 3 articles about tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 121353-12-6
tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

: 1730-25-2
allylmagnesium bromide

: 121353-13-7
tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

Guidance literature:: With copper(l) iodide; In tetrahydrofuran; diethyl ether; at 0 ℃; for 4h; Yield given;
DOI:10.1021/jo00273a009

Reference yield:

: 51442-80-9
5-(tetrahydro-2H-pyran-2-yloxy)-2-pentyn-1-ol

: 121353-13-7
tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Red-Al, 2.) I₂ / 1.) ether, toluene, RT, 1 h, 2.) from -78 deg C to RT, 2 h

2: imidazole / dimethylformamide / 1.) 0 deg C, 30 min, 2.) RT, 5 min

3: CuI / tetrahydrofuran; diethyl ether / 4 h / 0 °C

With 1H-imidazole; copper(l) iodide; iodine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00273a009

Reference yield:

: 121353-11-5
(Z)-3-iodo-5-(tetrahydro-2H-pyran-2-yloxy)pent-2-en-1-ol

: 121353-13-7
tert-Butyl-diphenyl-{(E)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-hexa-2,5-dienyloxy}-silane

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole / dimethylformamide / 1.) 0 deg C, 30 min, 2.) RT, 5 min

2: CuI / tetrahydrofuran; diethyl ether / 4 h / 0 °C

With 1H-imidazole; copper(l) iodide; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00273a009