tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane
CAS No.:121353-12-6
Molecular Formula:C₂₆H₃₅IO₃Si
Molecular Weight:550.552
Hs Code.:

Synonyms:tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

Suppliers and Price of tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

There total 2 articles about tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 121353-11-5
(Z)-3-iodo-5-(tetrahydro-2H-pyran-2-yloxy)pent-2-en-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 121353-12-6
tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

Guidance literature:: With 1H-imidazole; In tetrahydrofuran; for 16h; Ambient temperature;
DOI:10.1016/S0040-4039(97)00871-X

Reference yield:

: 92844-99-0
(2E)-5-<(2-tetrahydropyranyl)oxy>pent-2-en-1-ol

: 121353-12-6
tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: NIS / tetrahydrofuran / -78 °C

2: imidazole / tetrahydrofuran

With 1H-imidazole; N-iodo-succinimide; In tetrahydrofuran;
DOI:10.1055/s-1999-2711

Reference yield: 88.0%

: 121353-12-6
tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane

: 105-36-2
ethyl bromoacetate

: 192370-24-4
(Z)-5-(tert-Butyl-diphenyl-silanyloxy)-3-[2-(tetrahydro-pyran-2-yloxy)-ethyl]-pent-3-enoic acid ethyl ester

Guidance literature:: ethyl bromoacetate; With zinc; In various solvent(s); for 0.5h; Heating;

tert-Butyl-[(Z)-3-iodo-5-(tetrahydro-pyran-2-yloxy)-pent-2-enyloxy]-diphenyl-silane; With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; tetrakis(triphenylphosphine) palladium⁽⁰⁾; at 65 ℃; for 2h;
DOI:10.1081/NCN-120022838