(E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

Base Information

Chemical Name:(E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane
CAS No.:1361598-53-9
Molecular Formula:C₂₅H₃₅BO₂Si
Molecular Weight:406.448
Hs Code.:

Synonyms:(E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

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Chemical Property of (E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

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Technology Process of (E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

There total 2 articles about (E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 451-40-1
phenyl benzyl ketone

: 1361598-48-2
[2,2-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl]trimethylsilane

: 1361598-53-9
(E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

Guidance literature:: [2,2-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl]trimethylsilane; With lithium 2,2,6,6-tetramethylpiperazide; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

phenyl benzyl ketone; In tetrahydrofuran; at 0 - 20 ℃; for 17h; stereoselective reaction;
DOI:10.1246/cl.2011.1440

Reference yield:

: 78782-17-9
4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane

: 1361598-53-9
(E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium 2,2,6,6-tetramethylpiperazide; N,N,N,N,-tetramethylethylenediamine / tetrahydrofuran / 2 h / -78 - 0 °C

1.2: 1 h / -78 - 20 °C

2.1: lithium 2,2,6,6-tetramethylpiperazide / tetrahydrofuran / 0.08 h / 0 °C

2.2: 17 h / 0 - 20 °C

With N,N,N,N,-tetramethylethylenediamine; lithium 2,2,6,6-tetramethylpiperazide; In tetrahydrofuran;
DOI:10.1246/cl.2011.1440

Reference yield: 55.0%

: 696-62-8
para-iodoanisole

: 1361598-53-9
(E)-[3,4-diphenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-en-1-yl]trimethylsilane

: 1361598-60-8
(E)-(2-(4-methoxyphenyl)-3,4-diphenylbut-2-en-1-yl)trimethylsilane

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium hydroxide; In 1,4-dioxane; at 60 ℃; for 24h;
DOI:10.1246/cl.2011.1440