(-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

Base Information

Chemical Name:(-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one
CAS No.:960294-55-7
Molecular Formula:C₄₃H₆₂O₅Si₂
Molecular Weight:715.133
Hs Code.:

(-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

Synonyms:(-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

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Chemical Property of (-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

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Technology Process of (-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

There total 1 articles about (-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 960294-54-6
C₄₃H₆₄O₅Si₂

: 960294-55-7
(-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

Guidance literature:: With dipyridinium dichromate; 4 A molecular sieve; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1002/anie.200702056

Reference yield: 83.0%

: 960294-55-7
(-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one

: 1822-00-0
trimethylsilylmethyllithium

: 960294-56-8
(-)-1-(((1R,2S,3R)-2-(tert-butyldimethylsilyloxy)-3-((tert-butyldiphenylsilyloxy)methyl)-3-(4,4-dimethylhepta-1,6-dien-2-yl)cyclobutyloxy)methyl)-4-methoxybenzene

Guidance literature:: (-)-1-((1R,2S,3R)-3-(4-methoxybenzyloxy)-2-(tert-butyldimethylsilyloxy)-1-((tert-butyldiphenylsilyloxy)methyl)cyclobutyl)-3,3-dimethylhex-5-en-1-one; trimethylsilylmethyllithium; In toluene; pentane; at -78 ℃; for 2h;

With toluene-4-sulfonic acid; In benzene; at 20 ℃; for 5h; Further stages.;
DOI:10.1002/anie.200702056