[FeCl((C₅H₂N(C₆H₂(CH₃)3))3(C₅H₂N(C₆H₂(C(CH₃)3)(O)(C(CH₃)2)C₆H₂(C(CH₃)3)CO₂CH₃)))]

Base Information

• Chemical Name: [FeCl((C₅H₂N(C₆H₂(CH₃)3))3(C₅H₂N(C₆H₂(C(CH₃)3)(O)(C(CH₃)2)C₆H₂(C(CH₃)3)CO₂CH₃)))]
• CAS No.: 331716-56-4
• Molecular Formula: C₇₂H₇₂ClFeN₄O₃
• Molecular Weight: 1132.69
• Mol file: 331716-56-4.mol

Synonyms:[FeCl((C₅H₂N(C₆H₂(CH₃)3))3(C₅H₂N(C₆H₂(C(CH₃)3)(O)(C(CH₃)2)C₆H₂(C(CH₃)3)CO₂CH₃)))]

Chemical Property of [FeCl((C₅H₂N(C₆H₂(CH₃)3))3(C₅H₂N(C₆H₂(C(CH₃)3)(O)(C(CH₃)2)C₆H₂(C(CH₃)3)CO₂CH₃)))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [FeCl((C₅H₂N(C₆H₂(CH₃)3))3(C₅H₂N(C₆H₂(C(CH₃)3)(O)(C(CH₃)2)C₆H₂(C(CH₃)3)CO₂CH₃)))]

There total 2 articles about [FeCl((C₅H₂N(C₆H₂(CH₃)3))3(C₅H₂N(C₆H₂(C(CH₃)3)(O)(C(CH₃)2)C₆H₂(C(CH₃)3)CO₂CH₃)))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

hydrogenchloride (7647-01-0,15364-23-5) + 5-[4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthenyl)]-10,15,20-trimesitylporphyrin + iron(II) bromide (7789-46-0) → [FeCl((C5H2N(C6H2(CH3)3))3(C5H2N(C6H2(C(CH3)3)(O)(C(CH3)2)C6H2(C(CH3)3)CO2CH3)))] (331716-56-4)

Guidance literature:

With 2,6-dimethylpyridine; air; In tetrahydrofuran; mixt. of porphyrin, 2,6-lutidine and FeBr2 in THF was refluxed under N2 for 5 h; opened to air; evapd. (vac.); chromd. (silica gel, CH2Cl2; MeOH/CH2Cl2);residue dissolved in CH2Cl2; stirred with aq. HCl for 1 h; org. layer w ashed (water); evapd.; residue chromd. (silica gel, CH2Cl2; MeOH/CH2Cl2); retreated with HCl; elem. anal.;

DOI:10.1021/ja028548o

Reference yield:

iron(II) chloride + 5-[4-(5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthenyl)]-10,15,20-trimesitylporphyrin → [FeCl((C5H2N(C6H2(CH3)3))3(C5H2N(C6H2(C(CH3)3)(O)(C(CH3)2)C6H2(C(CH3)3)CO2CH3)))] (331716-56-4)

Guidance literature:

With air; In N,N-dimethyl-formamide;

DOI:10.1021/acs.inorgchem.9b02348

Reference yield:

[FeCl((C5H2N(C6H2(CH3)3))3(C5H2N(C6H2(C(CH3)3)(O)(C(CH3)2)C6H2(C(CH3)3)CO2CH3)))] (331716-56-4) + iodosylbenzene (536-80-1) → [Fe(O)((C5H2N(C6H2(CH3)3))3(C5H2N(C6H2(C(CH3)3)(O)(C(CH3)2)C6H2(C(CH3)3)CO2CH3)))](1+)

Guidance literature:

In dichloromethane; Fe complex was treated with PhIO in CH2Cl2 at -78°C; not isolated; UV monitoring;

DOI:10.1021/ja028548o

upstream raw materials:

hydrogenchloride

iron(II) bromide