potassium (4-(methyl formate)benzyl)trifluoroborate

Base Information

• Chemical Name: potassium (4-(methyl formate)benzyl)trifluoroborate
• CAS No.: 1632070-91-7
• Molecular Formula: C₉H₉BF₃O₂*K
• Molecular Weight: 256.074
• Mol file: 1632070-91-7.mol

Synonyms:potassium (4-(methyl formate)benzyl)trifluoroborate

Chemical Property of potassium (4-(methyl formate)benzyl)trifluoroborate

Chemical Property:

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Technology Process of potassium (4-(methyl formate)benzyl)trifluoroborate

There total 1 articles about potassium (4-(methyl formate)benzyl)trifluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

potassium hydrogen difluoride + Methyl 4-(bromomethyl)benzoate (2417-72-3) + bis(pinacol)diborane (73183-34-3) → potassium (4-(methyl formate)benzyl)trifluoroborate (1632070-91-7)

Guidance literature:

Methyl 4-(bromomethyl)benzoate; bis(pinacol)diborane; With potassium acetate; Tri(p-tolyl)phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; at 50 ℃; for 24h; Inert atmosphere;

potassium hydrogen difluoride; In methanol; water; ethyl acetate; at 0 - 20 ℃; for 1.5h; Inert atmosphere;

DOI:10.1002/anie.201700097

Reference yield: 95.0%

potassium (4-(methyl formate)benzyl)trifluoroborate (1632070-91-7) + ethyl 5-methylbenzo[d]isothiazole-3-carboxylate 1,1-dioxide (150256-91-0) → C19H19NO6S

Guidance literature:

With copper(II) tetrafluoroborate monohydrate; C₅₃H₅₈N₂O₂; In chloroform; at -20 ℃; for 12h; enantioselective reaction; Inert atmosphere; Schlenk technique; Irradiation;

DOI:10.1021/jacs.8b09251

Reference yield: 86.0%

2,2,6,6-Tetramethyl-1-piperidinyloxy free radical (2564-83-2,45842-10-2,126517-51-9,25657-03-8,26933-82-4,54637-06-8,64104-42-3) + potassium (4-(methyl formate)benzyl)trifluoroborate (1632070-91-7) → methyl 4-[[(2,2,6,6-tetramethyl-1-piperidinyl)oxy]methyl]benzoate

Guidance literature:

With lithium perchlorate; In N,N-dimethyl-formamide; at 20 ℃; Electrochemical reaction; Inert atmosphere; Glovebox;

DOI:10.1002/anie.202014244

upstream raw materials:

Methyl 4-(bromomethyl)benzoate

bis(pinacol)diborane

Downstream raw materials:

methyl 4-(4-cyanobenzyl)benzoate

methyl 4-(3-(ethoxycarbonyl)but-3-en-1-yl)benzoate