N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

Base Information

Chemical Name:N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide
CAS No.:312283-46-8
Molecular Formula:C₃₁H₄₄N₆O₁₂S₂
Molecular Weight:756.855
Hs Code.:

Synonyms:N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

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Chemical Property of N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

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Technology Process of N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

There total 5 articles about N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 312283-45-7
N-(2-nitrobenzenesulfonyl)-N'-(allyloxycarbonyl)-1,3-diaminopropane

: 312283-44-6
8-tert-butoxycarbonylamino-5-(2-nitrobenzenesulfonyl)-5-azaoctan-1-yl bromide

: 312283-46-8
N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

Guidance literature:: With tetra-(n-butyl)ammonium iodide; caesium carbonate; In acetonitrile; at 60 ℃; for 1h;
DOI:10.1248/cpb.48.1570

Reference yield:

: 1694-92-4
2-Nitrobenzenesulfonyl chloride

: 312283-46-8
N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

Guidance literature:: Multi-step reaction with 4 steps

1: 83 percent / ethanol / 0.5 h

2: 99 percent / Et₃N / CH₂Cl₂ / 1 h / 20 °C

3: 81 percent / K₂CO₃ / dimethylformamide / 0.5 h / 60 °C

4: 97 percent / Cs₂CO₃; nBu₄NI / acetonitrile / 1 h / 60 °C

With tetra-(n-butyl)ammonium iodide; potassium carbonate; caesium carbonate; triethylamine; In ethanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1248/cpb.48.1570

Reference yield:

: 240423-09-0
N-(6-aminopropyl)-2-nitrobenzenesulfonamide

: 312283-46-8
N-(12-allyloxycarbonylamino-4,9-bis(2-nitrobenzenesulfonyl)-4,9-diazadodecan-1-yl)-tert-butoxycarbamide

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / Et₃N / CH₂Cl₂ / 1 h / 20 °C

2: 81 percent / K₂CO₃ / dimethylformamide / 0.5 h / 60 °C

3: 97 percent / Cs₂CO₃; nBu₄NI / acetonitrile / 1 h / 60 °C

With tetra-(n-butyl)ammonium iodide; potassium carbonate; caesium carbonate; triethylamine; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1248/cpb.48.1570