(η4-C5H6)Re(PPh3)2H3

Base Information

Chemical Name:(η4-C5H6)Re(PPh3)2H3
CAS No.:108101-07-1
Molecular Formula:C₄₁H₃₉P₂Re
Molecular Weight:779.915
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η4-C5H6)Re(PPh3)2H3

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Technology Process of (η4-C5H6)Re(PPh3)2H3

There total 3 articles about (η4-C5H6)Re(PPh3)2H3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: 12103-36-5
Re(P(C₆H₅)3)2H₅

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 108101-07-1,81368-84-5
(η4-C5H6)Re(PPh3)2H3

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); a soln. of Re-complex and cyclopentadiene irradiated at 0°C for 15 min; ether added;

Reference yield:

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 108101-07-1,81368-84-5
(η4-C5H6)Re(PPh3)2H3

: (C₅H₅)Re(P(C₆H₅)3)2H₂

Guidance literature:: In tetrahydrofuran-d8; byproducts: cyclopentene; the hydride complex reacted with 2 equiv of cyclopentadiene at 60°C during 5 min; identified by NMR spectrum;
DOI:10.1021/ja00301a029

Reference yield:

: 12104-75-5,122169-15-7
pentahydridotris(triphenylphosphane)Re(V)

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 108101-07-1,81368-84-5
(η4-C5H6)Re(PPh3)2H3

Guidance literature:: In tetrahydrofuran-d8; Irradiation (UV/VIS); irradiation through a 328-nm band pass filter at 0°C under inert atmosphere in a sealed NMR tube for 15 min; reaction was followed by (1)H NMR spectroscopy; starting material and (η4-C5H6)Re(PPh3)2H3 in 1 : 9 molar ratio were obtained upon pptn. with Et2O;