phenyliodonium bis(phenylsulfonyl)-methylide

Base Information

• Chemical Name: phenyliodonium bis(phenylsulfonyl)-methylide
• CAS No.: 121434-38-6
• Molecular Formula: C₁₉H₁₅IO₄S₂
• Molecular Weight: 498.362
• Mol file: 121434-38-6.mol

Synonyms:phenyliodonium bis(phenylsulfonyl)-methylide

Chemical Property of phenyliodonium bis(phenylsulfonyl)-methylide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenyliodonium bis(phenylsulfonyl)-methylide

There total 1 articles about phenyliodonium bis(phenylsulfonyl)-methylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + bis(phenylsulfonyl)methane (3406-02-8) → phenyliodonium bis(phenylsulfonyl)-methylide (121434-38-6)

Guidance literature:

With potassium hydroxide; In methanol; at -10 ℃;

DOI:10.1021/ja00310a072

Reference yield: 80.0%

phenyliodonium bis(phenylsulfonyl)-methylide (121434-38-6) → S-Phenyl benzenethiosulfonate (1212-08-4)

Guidance literature:

With copper acetylacetonate; In tert-butyl alcohol; Heating;

DOI:10.1021/ja00310a072

Reference yield: 80.0%

phenyliodonium bis(phenylsulfonyl)-methylide (121434-38-6) → iodobenzene (591-50-4) + S-Phenyl benzenethiosulfonate (1212-08-4)

Guidance literature:

copper acetylacetonate; In tert-butyl alcohol; for 5h; Heating;

DOI:10.1039/P19880002839

upstream raw materials:

[bis(acetoxy)iodo]benzene

bis(phenylsulfonyl)methane

Downstream raw materials:

2-(bis(phenylsulfonyl)methyl)thiophene

1,1-bis(phenylsulfonyl)-1-(pyridinio)methanide

2-(bis(phenylsulfonyl)methyl)-5-methylthiophene

iodobenzene

Refernces

• 1、 Gogonas, Efstathios P.,Nyxas, Ioannis,Hadjiarapoglou, Lazaros P.. "The reaction of phenyliodonium bis(phenylsulfonyl)methylide with alkyl iodides". . p. 2563 - 2565. Retrieved 2004.
• 2、 Hatjiarapoglou, Lazaros,Varvoglis, Anastassios,Alcock, Nathaniel W.,Pike, Graham A.. "REACTIVITY OF PHENYLIODONIUM BIS(ARYLSULPHONYL)METHYLIDES TOWARDS ALKENES AND ALKYNES: CRYSTAL STRUCTURE OF 9-PHENYLSULPHONYL-1,2,3,4,4a,9a-HEXAHYDRO-1,4-METHANOFLUORENE". . p. 2839 - 2846. Retrieved 2007/10/02.