Cu^I(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline)

Base Information

• Chemical Name: Cu^I(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline)
• CAS No.: 828935-28-0
• Molecular Formula: C₃₂H₂₇CuIN₂P
• Molecular Weight: 661.004
• Mol file: 828935-28-0.mol

Synonyms:Cu^I(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline)

Chemical Property of Cu^I(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cu^I(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline)

There total 2 articles about Cu^I(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

copper(l) iodide (7681-65-4) + 2.9-dimethyl-1,10-phenanthroline (484-11-7) + triphenylphosphine (603-35-0) → CuI(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline) (828935-28-0)

Guidance literature:

In dichloromethane; toluene; at 80 ℃;

DOI:10.1016/j.ica.2020.120241

Reference yield:

copper(l) iodide (7681-65-4) + 2,9-dimethyl-1,10-phenanthroline hemihydrate (34302-69-7) + triphenylphosphine (603-35-0) → CuI(triphenylphosphine)(2,9-dimethyl-1,10-phenanthroline) (828935-28-0)

Guidance literature:

In chloroform; (N2, Schlbnek technique); addn. of 1 equiv. of copper iodide and 1 equiv. of phenanthroline deriv. to CHCl3 soln. of 2 equiv. of phosphine deriv., stirring at room temp. for 3 h; evapn., drying at 40°C in vac. for several hs, dissolving in CH2Cl2/acetone mixt., keeping at -18°C, filtration, drying at 40°C in vac. for several hs, elem. anal.;

DOI:10.1039/c0dt01284j

upstream raw materials:

copper(l) iodide

2,9-dimethyl-1,10-phenanthroline hemihydrate

triphenylphosphine

2.9-dimethyl-1,10-phenanthroline