Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)-

Base Information

Chemical Name:Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)-
CAS No.:1152785-19-7
Molecular Formula:C₁₀H₁₅BrOSi
Molecular Weight:259.218
Hs Code.:
DSSTox Substance ID:DTXSID901260446

Synonyms:1152785-19-7;Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)-;2-Bromo-6-(trimethylsilyl)anisole;SCHEMBL5090600;DTXSID901260446;(3-Bromo-2-methoxyphenyl)trimethylsilane;SY329666;1-Bromo-2-methoxy-3-(trimethylsilyl)benzene

Suppliers and Price of Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:258.00755
Heavy Atom Count:13
Complexity:167

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=C(C=CC=C1Br)[Si](C)(C)C

Technology Process of Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)-

There total 2 articles about Benzene, 1-bromo-2-methoxy-3-(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 75-77-4
chloro-trimethyl-silane

: 38603-09-7
2,6-dibromoanisole

: 1152785-19-7
1-bromo-2-methoxy-3-(trimethylsilyl)benzene

Guidance literature:: 2,6-dibromoanisole; With n-butyllithium; In diethyl ether; at 0 ℃; for 0.5h; Inert atmosphere;

chloro-trimethyl-silane; In diethyl ether; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/adsc.200800363

Reference yield: 32.0%

: 704-43-8
(2-methoxy-phenyl)-trimethyl-silane

: 1152785-19-7
1-bromo-2-methoxy-3-(trimethylsilyl)benzene

Guidance literature:: (2-methoxy-phenyl)-trimethyl-silane; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In diethyl ether; at 0 - 20 ℃; Inert atmosphere;

With bromine; In diethyl ether; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/adsc.200800363

Reference yield: 99.0%

: 1152785-19-7
1-bromo-2-methoxy-3-(trimethylsilyl)benzene

: (2S_P,4R,5S)-(-)-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazaphospholidine borane

: (R(P))-[(1S,2R)-N-ephedrino](phenyl)(6-trimethylsilyl-2-anisyl)phosphine-P-borane

Guidance literature:: 1-bromo-2-methoxy-3-(trimethylsilyl)benzene; With BuLi (n, s or t); at 0 - 20 ℃; Inert atmosphere;

(2S_P,4R,5S)-(-)-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazaphospholidine borane; In tetrahydrofuran; at -30 - 20 ℃; Inert atmosphere;
DOI:10.1002/adsc.200800363