phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

Base Information

Chemical Name:phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside
CAS No.:922183-04-8
Molecular Formula:C₃₀H₄₃O₈PSSi
Molecular Weight:622.792
Hs Code.:

Synonyms:phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

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Chemical Property of phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

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Technology Process of phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

There total 3 articles about phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 922183-04-8
phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: di-n-butyltin oxide / toluene / 2 h / 110 °C

1.2: 100 percent / tetrabutylammonium iodide / dimethylformamide / 12 h

2.1: 95 percent / NaH / various solvent(s); tetrahydrofuran / 10 h / 20 °C

With sodium hydride; di(n-butyl)tin oxide; In tetrahydrofuran; toluene;
DOI:10.1002/anie.200602699

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 922183-04-8
phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / phosphorus oxychloride; triethylamine / CH₂Cl₂ / 0.5 h / 0 °C

2: 95 percent / NaH / various solvent(s); tetrahydrofuran / 10 h / 20 °C

With sodium hydride; triethylamine; trichlorophosphate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.200602699

Reference yield:

: 159407-19-9
phenyl 4,6-O-benzylidene-1-thio-α-D-mannopyranoside

: 922183-04-8
phenyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-2-O-(2,2-dimethyltrimethylenephosphornoyl)-α-D-thiomannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: di-n-butyltin oxide / toluene / 2 h / 110 °C

1.2: 100 percent / tetrabutylammonium iodide / dimethylformamide / 12 h

2.1: 95 percent / NaH / various solvent(s); tetrahydrofuran / 10 h / 20 °C

With sodium hydride; di(n-butyl)tin oxide; In tetrahydrofuran; toluene;
DOI:10.1002/anie.200602699