1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene

Base Information

• Chemical Name: 1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene
• CAS No.: 78055-70-6
• Molecular Formula: C₁₃H₂₆Si
• Molecular Weight: 210.435
• DSSTox Substance ID: DTXSID501218312
• Nikkaji Number: J452.772K,J864.085H
• Mol file: 78055-70-6.mol

Synonyms:geranyltrimethylsilane;DTXSID501218312;1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene;[(E)-3,7-Dimethyl-2,6-octadienyl]trimethylsilane;[(2E)-3,7-Dimethyl-2,6-octadien-1-yl]trimethylsilane;78055-70-6

Chemical Property of 1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 210.180377364
• Heavy Atom Count: 14
• Complexity: 212

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=CCCC(=CC[Si](C)(C)C)C)C
• Isomeric SMILES: CC(=CCC/C(=C/C[Si](C)(C)C)/C)C

Technology Process of 1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene

There total 4 articles about 1-Trimethylsilyl-3,7-dimethyl-2,6-octadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

trimethylsilyllithium (18000-27-6) + 1-chloro-3,7-dimethylocta-2,6-diene (5389-87-7) → trimethyl[(E)-3,7-dimethylocta-2,6-dienyl]silane (78055-70-6)

Guidance literature:

In tetrahydrofuran; at -70 - 20 ℃;

DOI:10.1016/S0040-4039(00)97523-3

Reference yield: 59.0%

chloro-trimethyl-silane (75-77-4) + 1-chloro-3,7-dimethylocta-2,6-diene (5389-87-7) → trimethyl[(E)-3,7-dimethylocta-2,6-dienyl]silane (78055-70-6)

Guidance literature:

With tetraethylammonium tosylate; In N,N-dimethyl-formamide; Ambient temperature; electrochemical reduction;

DOI:10.1021/jo00371a016

Reference yield:

trimethylsilyllithium (18000-27-6) + 1-chloro-3,7-dimethylocta-2,6-diene (5389-87-7) → trimethyl[(E)-3,7-dimethylocta-2,6-dienyl]silane (78055-70-6) + (1,5-Dimethyl-1-vinyl-hex-4-enyl)-trimethyl-silane (85956-58-7)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; at -60 - -50 ℃; for 1h; Product distribution;

DOI:10.1021/jo00196a002

upstream raw materials:

chloro-trimethyl-silane

1-chloro-3,7-dimethylocta-2,6-diene

trimethylsilyllithium

(Trimethylsilyl)copper

Downstream raw materials:

3,7-dimethylocta-1,6-dien-3-ol

Geraniol

3,7-dimethyl-2E,6-octadien-1-yl acetate

linalool acetate