(η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride

Base Information

Chemical Name:(η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride
CAS No.:84500-10-7
Molecular Formula:BF₄*CH₂Cl₂*C₅₂H₄₂IrP₂
Molecular Weight:1092.81
Hs Code.:

Synonyms:(η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride

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Technology Process of (η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride

There total 1 articles about (η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 14104-20-2
silver tetrafluoroborate

: 84500-08-3
dichlorobis(η4-dibenzo[a,e]cyclooctatetraene)diiridium(I)

: 84500-10-7
(η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride

Guidance literature:: With PPh₃; In dichloromethane; byproducts: AgCl; to CH2Cl2 soln. of Ir complex and PPh3 added AgBF4, stirred for 10 min,filtered off AgCl, concd., added hexane and diethyl ether (3:1) to formsecond layer, kept for 1 d; filtered, washed with Et2O, elem. anal.;
DOI:10.1021/om00077a009

Reference yield: 30.0%

: 84500-10-7
(η4-dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I) tetrafluoroborate-methylene chloride

: 22560-16-3
lithium triethylborohydride

: 84500-13-0
hydrido(dibenzo[a,e]cyclooctatetraene)bis(triphenylphosphine)iridium(I)

Guidance literature:: In tetrahydrofuran; dichloromethane; to soln. of Ir complex in CH2Cl2/THF at 0°C added THF soln. of LiBHEt3 slowly, stirred for 15 min; solvent removed, residue dissolved in CH2Cl2, filtered, MeOH/H2O (2:1) added as upper layer, filtered, washed with cold MeOH, dried;
DOI:10.1021/om00077a009