2-iodophenyl methacrylate

Base Information

• Chemical Name: 2-iodophenyl methacrylate
• CAS No.: 135740-16-8
• Molecular Formula: C₁₀H₉IO₂
• Molecular Weight: 288.085
• Mol file: 135740-16-8.mol

Synonyms:2-iodophenyl methacrylate

Chemical Property of 2-iodophenyl methacrylate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-iodophenyl methacrylate

There total 1 articles about 2-iodophenyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 2-Iodophenol (533-58-4) → 2-iodophenyl methacrylate (135740-16-8)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1021/jacs.0c07492

Reference yield: 93.0%

2-iodophenyl methacrylate (135740-16-8) + phenylacetylene (536-74-3) → 2-(phenylethynyl)phenyl methacrylate (1603105-59-4)

Guidance literature:

With bis(triphenylphosphine)palladium(II) dichloride; triethylamine; copper(l) chloride; In toluene; at 20 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201303879

Reference yield: 86.0%

2-iodophenyl methacrylate (135740-16-8) + tert-butyl alcohol (75-65-0) → 2-iodophenyl 2,4,4-trimethylpentanoate

Guidance literature:

With cyclopentadienyl titanium(IV) trichloride; triethylsilyl chloride; zinc; In tetrahydrofuran; at 60 ℃; for 12h; chemoselective reaction; Molecular sieve; Sealed tube; Inert atmosphere;

DOI:10.1021/jacs.0c07492

upstream raw materials:

poly(methacrylic acid)

2-Iodophenol

Downstream raw materials:

2-(phenylethynyl)phenyl methacrylate