trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

Base Information

Chemical Name:trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate
CAS No.:125974-14-3
Molecular Formula:C₂₇H₃₈O₃Si
Molecular Weight:438.682
Hs Code.:

Synonyms:trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

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Chemical Property of trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

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Technology Process of trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

There total 3 articles about trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 125974-13-2
cis-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopenten-1-ol

: 65-85-0,8013-63-6
benzoic acid

: 125974-14-3
trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; Ambient temperature;
DOI:10.1021/jo00296a076

Reference yield:

: 7129-41-1
6-oxabicyclo[3.1.0]hex-2-ene

: 125974-14-3
trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 1.28 M n-BuLi / 1) hexane, 0 deg C, 15 min, 2) rt

2: 88 percent / Ph₃P, diethyl azodicarboxylate / tetrahydrofuran / Ambient temperature

With n-butyllithium; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran;
DOI:10.1021/jo00296a076

Reference yield:

: 91098-88-3
(3S)-3-(tert-butyldimethyl-siloxy)-3-cyclohexylprop-1-yne

: 125974-14-3
trans-4-(3-((tert-Butyldimethylsilyl)oxy)-3-cyclohexyl-1-propynyl)-2-cyclopentenyl Benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 1.28 M n-BuLi / 1) hexane, 0 deg C, 15 min, 2) rt

2: 88 percent / Ph₃P, diethyl azodicarboxylate / tetrahydrofuran / Ambient temperature

With n-butyllithium; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran;
DOI:10.1021/jo00296a076