4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene

Base Information

• Chemical Name: 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene
• CAS No.: 1026805-54-8
• Molecular Formula: C₂₀H₁₉FeN₃O
• Molecular Weight: 373.237
• Mol file: 1026805-54-8.mol

Synonyms:4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene

Chemical Property of 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene

There total 2 articles about 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

ferroceneacetylene (1271-47-2) + 1-(azidomethyl)-4-methoxybenzene (70978-37-9) → 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene (1026805-54-8)

Guidance literature:

With sodium hydride; In tetrahydrofuran; byproducts: H2, NaCl; Ar, NaH (1 equiv.) added to THF soln. of ligand, stirred to termination of H2 evolution, metal compd. (0.5 equiv.) added, stirred for 16 h at room temp.; evapd. (vac.), suspnd. (CH2Cl2), filtered over Na2SO4, evapd., residue washed (pentane), dried (vac.), elem. anal.;

DOI:10.1016/j.molcata.2008.04.005

Reference yield:

[PdCl2(p-methoxybenzyl-1,2,3-triazolylferrocene)2] (1026805-62-8) → 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene (1026805-54-8)

Guidance literature:

In dimethylsulfoxide-d6; equil. in soln.; not isolated, detected by NMR;

DOI:10.1021/ic8002405

Reference yield:

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 4-methoxy-1-(4-ferrocenyl-1,2,3-triazol-1-ylmethyl)benzene (1026805-54-8) → [PdCl2(p-methoxybenzyl-1,2,3-triazolylferrocene)2] (1026805-62-8)

Guidance literature:

In dimethylsulfoxide-d6; Pd compd. added to a soln. of Fe complex; not isolated, detected by NMR;

DOI:10.1021/ic8002405

upstream raw materials:

ferroceneacetylene

1-(azidomethyl)-4-methoxybenzene

[PdCl₂(p-methoxybenzyl-1,2,3-triazolylferrocene)2]

Downstream raw materials:

[PdCl₂(p-methoxybenzyl-1,2,3-triazolylferrocene)2]