2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

Base Information

Chemical Name:2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene
CAS No.:944382-61-0
Molecular Formula:C₁₇H₂₃ClO₃
Molecular Weight:310.821
Hs Code.:

Synonyms:2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

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Chemical Property of 2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

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Technology Process of 2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

There total 7 articles about 2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 944382-82-5
C₁₇H₂₄O₄

: 944382-61-0
2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

Guidance literature:: With N-chloro-succinimide; potassium carbonate; triphenylphosphine; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1039/b703373g

Reference yield:

: 944382-60-9
2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohex-6-en-1-yl-trifluoromethanesulphonate

: 944382-61-0
2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

Guidance literature:: Multi-step reaction with 5 steps

1: (bis)-triphenylphosphine palladium (II) chloride / tetrahydrofuran; pentane / 5 h / Heating

2: 6.1 g / pyridinium p-toluenesulfonate / methanol / 48 h / 20 °C

3: 96 percent / triethylamine; 4-dimethylaminopyridine / CH₂Cl₂ / 6 h / 0 °C

4: 98 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 1.5 h / 20 °C

5: 94 percent / N-chlorosuccinimide; triphenylphosphine; potassium carbonate / CH₂Cl₂ / 0.5 h / 0 °C

With dmap; N-chloro-succinimide; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; potassium carbonate; triethylamine; triphenylphosphine; (bis)-triphenylphosphine palladium (II) chloride; In tetrahydrofuran; methanol; dichloromethane; pentane; 1: Stille coupling reaction;
DOI:10.1039/b703373g

Reference yield:

: 145386-47-6
2-(2'-tert-butyldimethylsilyloxy-ethan-1'-yl)-cyclohexan-1-one

: 944382-61-0
2-(2'''-acetoxy-ethan-1'''-yl)-1-[5'-(3''-chloro-propan-1''-yl)-2'-furanyl]cyclohex-6-ene

Guidance literature:: Multi-step reaction with 6 steps

1.1: diisopropylamine; n-butyllithium / tetrahydrofuran / 2 h / -78 - 20 °C

1.2: 99 percent / tetrahydrofuran / 3 h / -78 - 0 °C

2.1: (bis)-triphenylphosphine palladium (II) chloride / tetrahydrofuran; pentane / 5 h / Heating

3.1: 6.1 g / pyridinium p-toluenesulfonate / methanol / 48 h / 20 °C

4.1: 96 percent / triethylamine; 4-dimethylaminopyridine / CH₂Cl₂ / 6 h / 0 °C

5.1: 98 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 1.5 h / 20 °C

6.1: 94 percent / N-chlorosuccinimide; triphenylphosphine; potassium carbonate / CH₂Cl₂ / 0.5 h / 0 °C

With dmap; N-chloro-succinimide; n-butyllithium; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; potassium carbonate; triethylamine; diisopropylamine; triphenylphosphine; (bis)-triphenylphosphine palladium (II) chloride; In tetrahydrofuran; methanol; dichloromethane; pentane; 2.1: Stille coupling reaction;
DOI:10.1039/b703373g