1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

Base Information

Chemical Name:1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal
CAS No.:132292-26-3
Molecular Formula:C₂₁H₃₄O₅
Molecular Weight:366.498
Hs Code.:

Synonyms:1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

Chemical Property:

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Technology Process of 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

There total 1 articles about 1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 66500-55-8
cyclohexanone-4-carboxylic acid ethyleneacetal

: 92-68-2
4-cyclohexylcyclohexanone

: 132292-26-3
1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

Guidance literature:: With n-butyllithium; N-cyclohexylisopropylamine; Yield given. Multistep reaction; 1) r.t., 5.5 h 2) THF, r.t., 17 h;
DOI:10.1055/s-1990-27091

Reference yield: 82.0%

: 132292-26-3
1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

: 132292-27-4
4-(4'-cyclohexylcyclohexylidene)cyclohexanone ethylene ketal

Guidance literature:: With N,N-dimethylformamide dineopentyl acetal; In acetonitrile; 1) r.t , 1 h 2) reflux, 18 h;
DOI:10.1055/s-1990-27091

Reference yield:

: 132292-26-3
1-carboxy-1'-hydroxy-1,1':4',1''-tercyclohexan-4-one ethylene ketal

: 132292-31-0
trans-1,1':4',1-tercyclohexyl-4-one

Guidance literature:: Multi-step reaction with 4 steps

1: 82 percent / Me₂NCH(OCH₂CMe₃)2 / acetonitrile / 1) r.t , 1 h 2) reflux, 18 h

2: 91 percent / aq. 2 N HCl / tetrahydrofuran / 3.5 h / 45 °C

3: 40 percent / H₂ / 10percent Pd/C / ethyl acetate / 0.33 h / 827.4 Torr / Ambient temperature

4: 32 percent / H₂ / 10percent Pd/C / ethyl acetate / 3 h / Ambient temperature

With hydrogenchloride; hydrogen; N,N-dimethylformamide dineopentyl acetal; palladium on activated charcoal; In tetrahydrofuran; ethyl acetate; acetonitrile;
DOI:10.1055/s-1990-27091