Benzenemethanol, 2-(3-butenyl)- (9CI)

Base Information

• Chemical Name: Benzenemethanol, 2-(3-butenyl)- (9CI)
• CAS No.: 121089-46-1
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.232
• Mol file: 121089-46-1.mol

Synonyms:Benzenemethanol,2-(3-butenyl)- (9CI); 2-(3-Butenyl)benzyl alcohol

Chemical Property of Benzenemethanol, 2-(3-butenyl)- (9CI)

Chemical Property:

• PSA: 20.23000
• LogP: 2.29750

Purity/Quality:

[2-(3-Buten-1-yl)phenyl]methanol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenemethanol, 2-(3-butenyl)- (9CI)

There total 10 articles about Benzenemethanol, 2-(3-butenyl)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

C16H22O2 (1196708-17-4) → (2-(but-3-en-1-yl)phenyl)methanol (121089-46-1)

Guidance literature:

With toluene-4-sulfonic acid; In methanol; at 20 ℃;

DOI:10.1016/j.tetlet.2009.08.092

Reference yield: 78.0%

2-(but-3-en-1-yl)benzoic acid (89730-30-3) → (2-(but-3-en-1-yl)phenyl)methanol (121089-46-1)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 25 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c5cc10245f

Reference yield: 63.2%

2-(but-3-en-1-yl)benzaldehyde (70576-29-3) → (2-(but-3-en-1-yl)phenyl)methanol (121089-46-1)

Guidance literature:

With methanol; sodium tetrahydroborate; at 20 ℃; for 1h;

upstream raw materials:

2-(but-3-en-1-yl)benzoic acid

C₁₆H₂₂O₂

ortho-methylbenzoic acid

2-Iodobenzoic acid

Downstream raw materials:

(E)-2-(p-toluenesulfonyl)-2,3,6,7-tetrahydro-1H-benzo[c]azonine

Refernces

• 1、 -. "Pyrazolopyrimidine Macrocycles as Inhibitors of Human Immunodeficiency Virus Replication". . . Retrieved 2015/09/22.
• 2、 Li, Yang,Jardine, Katherine J.,Tan, Runyu,Song, Datong,Dong, Vy M.. "Palladium-catalyzed intramolecular carboesterification of olefins". supporting information; experimental part. p. 9690 - 9692. Retrieved 2010/04/28.