N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Base Information

Chemical Name:N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine
CAS No.:1616088-00-6
Molecular Formula:C₂₀H₂₁NO₄S
Molecular Weight:371.457
Hs Code.:

Synonyms:N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Suppliers and Price of N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

There total 6 articles about N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1377585-41-5
3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

: 140-88-5,9003-32-1
ethyl acrylate

: 1616088-00-6
N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Guidance literature:: With silver tetrafluoroborate; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate hydrate; In 1,2-dichloro-ethane; at 120 ℃; for 24h; Reagent/catalyst; Solvent; regioselective reaction; Inert atmosphere; Glovebox; Schlenk technique;
DOI:10.1021/jo5008465

Reference yield:

: 1377585-41-5
3-methyl-N-(methyl(oxo)(phenyl)-λ⁶-sulfanylidene)benzamide

: 140-88-5,9003-32-1
ethyl acrylate

: 1616088-00-6
N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

: 1616088-12-0
N-[2-(3-ethoxy-3-oxopropyl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Guidance literature:: With sodium hexaflorophosphate; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate hydrate; In 1,2-dichloro-ethane; at 120 ℃; for 24h; Reagent/catalyst; Solvent; regioselective reaction; Inert atmosphere; Glovebox; Schlenk technique;
DOI:10.1021/jo5008465

Reference yield:

: 1193-82-4
racemic methyl phenyl sulfoxide

: 1616088-00-6
N-[(E)-2-(3-ethoxy-3-oxoprop-1-en-1-yl)-5-methylbenzoyl]-S-methyl-S-phenylsulfoximine

Guidance literature:: Multi-step reaction with 3 steps

1: sodium azide; sulfuric acid / chloroform / Schlenk technique

2: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

3: [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate hydrate; silver tetrafluoroborate / 1,2-dichloro-ethane / 24 h / 120 °C / Inert atmosphere; Glovebox; Schlenk technique

With dmap; silver tetrafluoroborate; sodium azide; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate hydrate; sulfuric acid; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; chloroform; 1,2-dichloro-ethane;
DOI:10.1021/jo5008465