CH₃OC₆H₄CHNSOC(CH₃)3

Base Information

• Chemical Name: CH₃OC₆H₄CHNSOC(CH₃)3
• CAS No.: 849590-39-2
• Molecular Formula: C₁₂H₁₇NO₂S
• Molecular Weight: 239.338
• Mol file: 849590-39-2.mol

Synonyms:CH₃OC₆H₄CHNSOC(CH₃)3

Chemical Property of CH₃OC₆H₄CHNSOC(CH₃)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CH₃OC₆H₄CHNSOC(CH₃)3

There total 1 articles about CH₃OC₆H₄CHNSOC(CH₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

S-tert-butylsulfinimide (146374-27-8) + 4-methoxy-benzaldehyde (123-11-5) → (±)-N-(4-methoxybenzylidene)-2-methylpropane-2-sulfinamide (849590-39-2)

Guidance literature:

With pyrrolidine; In dichloromethane; at 60 ℃; for 4h; Molecular sieve;

DOI:10.1021/ja4111418

Reference yield: 90.0%

(±)-N-(4-methoxybenzylidene)-2-methylpropane-2-sulfinamide (849590-39-2) + [(p-methylphenyl)sulfonylmethyl]isonitrile (38622-91-2,36635-61-7) → 4(5)-(4-methoxyphenyl)-1H-imidazole (35512-31-3)

Guidance literature:

With potassium carbonate; In methanol; at 25 ℃; for 0.5h;

DOI:10.1016/j.tetlet.2020.151705

Reference yield: 83.0%

O-tert-butyl-1,2-dichloroenol ether (1379406-64-0) + (±)-N-(4-methoxybenzylidene)-2-methylpropane-2-sulfinamide (849590-39-2) → (SSRS,RS)-N-(3-(tert-butoxy)-1-(4-methoxyphenyl)prop-2-yn-1-yl)-2-methylpropane-2-sulfinamide

Guidance literature:

O-tert-butyl-1,2-dichloroenol ether; With n-butyllithium; In tetrahydrofuran; hexane; at -80 - -20 ℃; for 0.75h; Inert atmosphere;

(±)-N-(4-methoxybenzylidene)-2-methylpropane-2-sulfinamide; With boron trifluoride diethyl etherate; In tetrahydrofuran; hexane; at -80 - -15 ℃; for 3h; diastereoselective reaction; Inert atmosphere;

DOI:10.1021/ol302392k

upstream raw materials:

S-tert-butylsulfinimide

4-methoxy-benzaldehyde

Downstream raw materials:

cis-4-methoxystilbene

(Z)-1-bromo-4-(4-methoxystyryl)benzene

1-(4-methoxyphenyl)but-3-en-1-amine