CID 11115999

Base Information

• Chemical Name: CID 11115999
• CAS No.: 124330-23-0
• Molecular Formula: C4H14 Al N
• Molecular Weight: 103.143
• European Community (EC) Number: 628-156-0
• Mol file: 124330-23-0.mol

Synonyms:124330-23-0;aluminum;N,N-dimethylethanamine;Aluminum, (N,N-dimethylethanamine)trihydro-, (T-4)-;SCHEMBL924597

Chemical Property of CID 11115999

Chemical Property:

• Vapor Pressure: 495mmHg at 25°C
• Melting Point: 15°C
• Boiling Point: 50-55°C 0,05mm
• Flash Point: −4 °F
• PSA: 3.24000
• Density: 0.837 g/mL at 25 °C
• LogP: 0.90540
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 100.0706878
• Heavy Atom Count: 6
• Complexity: 17.6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Alane N,N-dimethylethylamine complex solution 0.5 M in toluene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C,Xn
• Statements: 11-14/15-34-48/20-63-65-67-36/38
• Safety Statements: 26-36/37/39-43-45-62-36/37-16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(C)C.[Al]
• Uses: Alane N,N-dimethylethylamine complex solution can be used as a selective reducing agent for the reduction of brominated γ-lactams to synthesize dihydroflustramine C and flustramine E alkaloids.

Technology Process of CID 11115999

There total 1 articles about CID 11115999 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

aluminum (III) chloride (7446-70-0,7784-13-6) + lithium aluminium tetrahydride (16853-85-3) + N,N-dimethyl-ethanamine (598-56-1) → alane-N,N-dimethylethylamine complex (124330-23-0)

Guidance literature:

In toluene; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1039/d0dt01820a

Reference yield: 97.0%

alane-N,N-dimethylethylamine complex (124330-23-0) + 2,2',3,3',4,4',5,5',6,6'-decafluorodiphenylamine (1535-92-8) → [(C6F5)2N]AlH2*NEtMe2 (936111-86-3)

Guidance literature:

In toluene; uncer N2 atm. soln. (C6F5)2NH in toluene was added dropwise to soln. AlH3*NEtMe2 in toluene (1:1) at 25°C and stirred overnight; solvent was removed in vacuo; elem. anal.;

DOI:10.1139/V07-003

Reference yield: 94.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + alane-N,N-dimethylethylamine complex (124330-23-0) + 2,6-diisopropylphenol (2078-54-8) → bis(2,6-diisopropylphenolato)aluminum hydride-bis(tetrahydrofuran) (193673-87-9)

Guidance literature:

In tetrahydrofuran; byproducts: EtNMe2, H2; Ar-atmosphere; dropwise addn. of 2 equiv. diisopropylphenol to Al-compd.(dry ice/Me2CO bath), stirring at room temp. for 3 d; solvent removal (vac.); elem. anal.;

DOI:10.1021/ic970171d

upstream raw materials:

aluminum (III) chloride

lithium aluminium tetrahydride

N,N-dimethyl-ethanamine

Downstream raw materials:

aluminium

2,6-(i-Pr)2C₆H₃N(H)Al(H)N(2,6-(i-Pr)2C₆H₃)AlH(NMe₂Et)N(H)C₆H₃-2,6-(i-Pr)2

bis(2,6-diisopropylphenolato)aluminum hydride-bis(tetrahydrofuran)

tris(2,6-diisopropylphenolato)(4-(dimethylethylammonium)butanato)aluminum

Refernces

• 1、 -. "ALUMINUM COMPOUND FOR FORMING ALUMINUM FILMS BY CHEMICAL VAPOR DEPOSITION AND THEIR SYNTHESIS". Page/Page column 17-18; 18-19. . Retrieved 2010/11/29.